|
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Refining
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RP 941
experience, of why some reformer furnaces have had problems with
Steels for Hydrogen Service at Elevated Temperatures and Pressures
embrittlement and cracking of outlet pigtails and manifold components in
service, while others have not had such problems. Pages: 53
in Petroleum Refineries and Petrochemical Plants
(includes Errata 1 dated June 2016, Errata 2 dated December 2017, and
1st Edition | June 2014 | Product Number: C942A01 | Price: $152.00
Addendum 1 dated August 2020)
TR 942-B
Summarizes the results of experimental tests and actual data acquired from
Material, Fabrication, and Repair Considerations for Austenitic Alloys
operating plants to establish practical operating limits for carbon and low
alloy steels in hydrogen service at elevated temperatures and pressures. The
Subject to Embrittlement and Cracking in High Temperature 565 °C
effects on the resistance of steels to hydrogen at elevated temperature and
to 760 °C (1050 °F to 1400 °F) Refinery Services
pressure that result from high stress, heat treating, chemical composition,
Focuses on the materials, fabrication, and repair of austenitic stainless
and cladding are discussed. This recommended practice (RP) does not
steels and nickel-iron-chromium alloys in high temperature 565 ºC to
address the resistance of steels to hydrogen at lower temperatures [below
760 ºC (1050 ºF to 1400 ºF) refinery services. Many of these alloys are
about 400 °F (204 °C)], where atomic hydrogen enters the steel as a result
subject to embrittlement and cracking after prolonged exposure to these
of an electrochemical mechanism.
temperatures. Susceptible equipment in the following processing units are
This RP applies to equipment in refineries, petrochemical facilities, and
addressed: fluid catalytic cracking units, hydrogen/syngas plants, catalytic
chemical facilities in which hydrogen or hydrogen-containing fluids are
reformers, cokers, and hydroprocessing units. This report summarizes
processed at elevated temperature and pressure. The guidelines in this RP
industry experience and recommends methods to improve reliability and
can also be applied to hydrogenation plants such as those that manufacture
process safety, and increases industry awareness to high temperature
ammonia, methanol, edible oils, and higher alcohols.
embrittlement issues.
The steels discussed in this RP resist high temperature hydrogen attack
As a basis of this report, technical literature, industry experience, and published
(HTHA) when operated within the guidelines given. However, they may not be
case studies were reviewed. The review included materials of construction,
resistant to other corrosives present in a process stream or to other
damage mechanisms, and component-specific fabrication and repair issues.
metallurgical damage mechanisms that can occur in the operating HTHA
range. This RP also does not address the issues surrounding possible
The scope of this report includes the following wrought austenitic alloys:
damage from rapid cooling of the metal after it has been in high temperature,
Alloys 800, 800H, 800HT, and 300 series austenitic stainless steels, and
high pressure hydrogen service (e.g. possible need for outgassing
corresponding welding consumables. Limits in chemical composition,
hydroprocessing reactors). This RP will discuss in detail only the resistance of
microstructural requirements, and heat treating practices that mitigate
steels to HTHA.
susceptibility to embrittlement and cracking are identified. Potentially viable
Presented in this document are curves that indicate the operating limits of
upgrades to commonly used alloys are identified where applicable.
temperature and hydrogen partial pressure for satisfactory resistance of
The remainder of this report is organized as follows: Section 3, Process Units,
carbon steel and Cr-Mo steels to HTHA in elevated temperature, hydrogen
gives a brief process overview followed by an explanation of the various
service. In addition, it includes a summary of inspection methods to evaluate
damage mechanisms found in that unit. Component specific considerations
equipment for the existence of HTHA. Pages: 45
and examples of in-service damage are also included. Inspection
8th Edition | February 2016 | Product Number: C94108 | Price: $152.00
recommendations and general repair method considerations are also
included. Section 4, Damage Mechanisms, contains detailed discussions of
high-temperature damage mechanisms, including fundamental details of the
TR 941-A
solid state reactions, their rate of reaction, and recommended mitigation
The Technical Basis Document for API RP 941
measures. Section 4 also incorporates fabrication and repair practices that
(includes Addendum 1 dated June 2019)
can be used for cracked or embrittled equipment. Pages: 88
Even before the first edition of API Publ 941, Steels for Hydrogen Service at
1st Edition | May 2017 | Effective Date: November 1, 2017
Elevated Temperatures and Pressures in Petroleum Refineries and
Product Number: C942B01 | Price: $187.00
Petrochemical Plants appeared in 1970, there had been fundamental
questions regarding the technical basis for the material performance curves
contained in the document (1-6). Based upon sparse laboratory data
RP 945
combined with plant experience, with only a few exceptions, the curves have
Avoiding Environmental Cracking in Amine Units
done an exceptionally good job at safely directing the refining industry in
selecting materials based upon operating temperature, hydrogen partial
Discusses environmental cracking problems of carbon steel equipment in
pressure, and the metallurgy of the equipment being considered. Pages: 301
amine units. This publication provides guidelines for carbon steel
construction materials, including, fabrication, inspection, and repair, to help
1st Edition | September 2008 | Product Number: C09410 | Price: $215.00
assure safe and reliable operation. The steels referred to in this document
are defined by the ASTM designation system, or equivalent materials
TR 942-A
contained in other recognized codes or standards. This document is based
Materials, Fabrication, and Repair Considerations for Hydrogen
on current engineering practices and insights from recent industry
Reformer Furnace Outlet Pigtails and Manifolds
experience. Pages: 46
Addresses materials, fabrication, and repair issues related to hydrogen and
4th Edition | September 2022 | Product Number: C94504 | Price: $110.00
syngas reformer furnace outlet pigtails and manifolds. High reliability of
outlet pigtails and manifold components, such as headers, tees, and fittings,
Publ 959
is important to the successful long-term operation of hydrogen and syngas
Characterization Study of Temper Embrittlement of Chromium-
reformer furnaces. These components typically operate at high temperatures
in the range of 750 to 950 °C (1382 to 1742 °F) where they are potentially
Molybdenum Steels
subject to high-temperature creep, stress relaxation, hot corrosion, and
Evaluates the temper embrittlement characteristics of Cr-Mo pressure vessel
thermal fatigue damage. In recent years a number of reformer furnace
steels. The steels are designated A387 in Part 4 of the ASTM Book of
operators have encountered problems of in-service degradation and
Standards. Most of the samples studied were of Grade 22 (2-1/4-1Mo) and a
cracking of outlet pigtails and manifold components, while others have had
few samples of Grades 11 and 21 were also included, (1-1/4Cr-1/2Mo, 3Cr-
little or no problems of this type. Both direct experience in addressing
1Mo). The 64 samples studied represented a wide range of commercially
specific cases of outlet pigtail and manifold cracking problems and indirect
available steel, including qualification welds in 1-in. and 6-in. steel plate, large
experience gained from surveying industry with regard to these problems
nozzle cut-outs, and randomly-shaped pieces of forging material. These
were used in preparing this report. The objective of the project was to
materials received heat treatment typical of hydro-treater reactor fabrication.
develop an understanding, based on published literature and industry
118
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Refining
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The objective of this program was to characterize typical commercial reactor
TR 977
steels and weldments in terms of toughness and other physical properties
ASTM C704 Test Variability Reduced to Allow Further Optimization of
prior to being placed in service and the changes anticipated in toughness
Erosion-Resistant Refractories for Critical Oil Refining Applications
due to long-time service at elevated temperatures.
It is important to note that the materials studied were typical of commercial
Documents the results of a joint project conducted by the API CRE
production and fabrication up to about 1975 and are not representative of
Subcommittee on Refractory Materials and the ASTM C08 Committee to
plate, forgings, and weld metal having low temper embrittlement
improve the reproducibility of the 2015 edition of ASTM C704/C704M,
susceptibility, generally available after 1975. Pages: 145
Standard Test Method for Abrasion Resistance of Refractory Materials at
Room Temperature. Erosion-resistant refractories are used in many oil
1st Edition | January 1982 | Product Number: C95900 | Price: $171.00
refining applications, such as Fluid Catalytic Cracking Units (FCCUs), to resist
the wearing effects of solids particles circulating at elevated velocities in a
RP 970
high-temperature process environment. This technical report also reviews the
Corrosion Control Documents
drivers for continuing improvement in erosion-resistant refractories and the
role of ASTM C704/C704M for the selection and installation quality control
Provides users with the basic elements for developing, implementing and
of refractories used in these installations. This report documents changes
maintaining a Corrosion Control Document (CCD) for refining, and at the
made to the setup and procedures to improve the reproducibility of the test.
owner's discretion, may be applied at petrochemical and chemical process
These changes are designed to achieve this end, while providing a rough
facilities. A CCD is a document or other repository or system that contains all
equivalency consistent with historical data before the changes were made.
the necessary information to understand materials damage susceptibility
These results are validated by the results of extensive international round-
issues in a specific type of operating process unit at a plant site.
robin and ruggedness testing, and are reported herein. Pages: 27
CCDs are a valuable addition to an effective Mechanical Integrity Program.
1st Edition | February 2018 | Product Number: C97701 | Price: $120.00
They help to identify the damage mechanism susceptibilities of pressure
containing piping and equipment, factors that influence damage mechanism
TR 978
susceptibilities, and recommended actions to mitigate the risk of loss of
Monolithic Refractories: Manufacture, Properties, and Selection
containment or unplanned outages.
Covers the installation and dryout of monolithic refractory lining materials for
This recommended practice serves as the basis for tracking CCD
Hydrocarbon Processing Industry (HPI) applications. It discusses the best
development, implementation, and maintenance to maintain consistency
practice procedures and techniques used in the installation of refractory
and to integrate the CCD work process with other plant integrity programs,
concrete, as well as those for air and heat setting plastics and ramming
such as Management of Change (MOC), Process Hazards Analysis (PHA),
mixes. In addition, it addresses the need for curing and dryout procedures to
and Reliability Centered Maintenance (RCM). Some of these programs have
achieve successful results. This instruction is consistent with API 936, which
significant overlap with the development of CCDs, including Risk-Based
is the HPI industry standard for the installation quality control of monolithic
Inspection studies (see RP 580 and RP 581), Integrity Operating Windows
refractories. Pages: 82
(see RP 584), in-house unit corrosion reviews, circuitization/systemization
programs, and similar types of corrosion studies. Development of CCDs can
1st Edition | March 2019 | Product Number: C97801 | Price: $115.00
serve as a useful starting point for establishing these programs if they have
not been undertaken.
TR 979
This recommended practice provides the owner/user with information and
Applications of Refractory Lining Materials
guidance on the work processes for development and implementation of
Covers the use of refractory concrete (castables), plastics, and ramming
CCDs for the owners’/users’ process units. Pages: 59
mixes for applications for the hydrocarbon processing industry (HPI). Its
1st Edition | December 2017 | Product Number: C97001 | Price: $202.00
content is complemented by the two other reports in this series:
API TR 978, Monolithic Refractories: Manufacture, Properties and
Std 975
Selection;
Refractory Installation Quality Control-Inspection and Testing of
API TR 980, Monolithic Refractories: Installation and Dryout.
Refractory Brick Systems and Materials
These technical reports update and add to the original reports written by
Committee 547 of the American Concrete Institute (ACI) in 1979 and 1989.
Provides installation quality control (QC) procedures for aluminum silicate
These are ACI 547.R-79, State-of-the Art Report: Refractory Concrete, and
dense and insulating fire brick refractory systems and may be used to
ACI 547.1R-89, State-of-the Art Report: Refractory Plastics and Ramming
supplement owner specifications. Materials, equipment, and personnel are
Mixes. TR 979 focuses specifically on the information on the applications of
qualified by the methods described, and applied refractory quality is closely
refractories contained in ACI 547.R-79 and ACI 547.1R-89.
monitored, based on defined procedures and acceptance criteria. The
The original content of these reports was focused primarily on steel- and
responsibilities of inspection personnel who monitor and direct the QC
glass-making applications, which represent the largest refractory markets.
process are also defined. Pages: 40
API, in tailoring the revision of this content to the HPI, has greatly expanded
1st Edition | November 2021 | Product Number: C97501 | Price: $94.00
the text pertaining to the specialized oil-refining and petrochemical-
processing applications. At the same time, API has retained and updated
Std 976
the information covering applications outside of the HPI (see Section 5)
Refractory Installation Quality Control-Inspection and Testing of
because of the similarities and applicability that this information has for
refractory professionals in these other industries. Pages: 63
AES/RCF Fiber Linings and Materials
1st Edition | October 2018 | Product Number: C97901 | Price: $135.00
Provides installation quality control procedures and lining system design
requirements for AES/RCF fiber linings and may be used to supplement
owner specifications. Materials, equipment, and personnel are qualified by
the methods described, and applied refractory quality is closely monitored,
based on defined procedures and acceptance criteria. The responsibilities of
inspection personnel who monitor and direct the quality control process are
also defined. The lining described in this standard is for internal refractory
linings on the process side of the equipment. External insulation and
jacketing are not covered in this standard. Pages: 34
1st Edition | March 2018 | Product Number: C97601 | Price: $131.00
This publication is a new entry in this catalog.
This publication is related to an API licensing, certification, or accreditation program.
119
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TR 980
Publ 4261
Monolithic Refractories: Installation and Dryout
Alcohols and Ethers: A Technical Assessment of Their Application as
Covers the installation and dryout of monolithic refractory lining materials for
Fuels and Fuel Components
hydrocarbon processing industry (HPI) applications. It discusses the best
Summarizes information from the technical literature on producing and
practice procedures and techniques used in the installation of refractory
applying alcohols and ethers as fuels and fuel components for the
concrete, as well as those for air-and heat-setting plastics and ramming
transportation sector. It assesses the technical advantages and
mixes. In addition, it discusses the need for curing and dryout and
disadvantages of alcohols and ethers with respect to hydrocarbon fuels.
procedures to achieve successful results. This instruction is consistent with
Since the amendment of the Clean Air Act in 1977, and subsequently in
Std 936, which is the HPI industry standard for the installation quality
1990, public interest in the role of oxygenates in transportation has
control of monolithic refractories. It also serves as the body of knowledge
significantly increased. This edition of Publ 4261 has been updated and
document for the API 936 Refractory Personnel Certification Program. This
expanded to include a review of the oxygenate regulations and the technical
report is the last in a series of three API reports covering the use of refractory
literature that has been published since 1988. It provides a technical
concrete (castables), plastics, and ramming mixes for applications for the
assessment suitable for policy discussions related to alcohols and ethers in
hydrocarbon processing industry. Its content is complemented by the two
transportation. Pages: 119
other reports in this series:
3rd Edition | June 2001 | Product Number: C42613 | Price: $176.00
API TR 978, Monolithic Refractories: Manufacture, Properties and
Selection, and
Publ 4262
API TR 979, Applications of Refractory Lining Materials. Pages: 66
Methanol Vehicle Emissions
1st Edition | April 2018 | Product Number: G98001 | Price: $157.00
December 1990 | Product Number: F42620 | Price: $136.00
TR 981
Thermal Expansion Under Load and Creep of Refractories-An
PROCESS SAFETY STANDARDS
Evaluation and Comparison of Testing Methods
RP 752
Documents the results of thermal expansion under load (TEUL) and creep in
compression testing conducted by ASTM C832 and DIN 993-9 (same test
Management of Hazards Associated with Location of Process Plant
as ISO 3187). The prime objective for this study is to determine if one or
Permanent Buildings
both tests should replace the ASTM C16 method. ASTM C16, modified from
Provides guidance for managing the risk from explosions, fires and toxic
1.5-hour to 100-hour hold, has been widely used to qualify brick for sulfur
material releases to on-site personnel located in new and existing buildings
reaction furnace use. In addition to deformation after 100 hours, the creep
intended for occupancy. This RP was developed for use at refineries,
tests will provide additional information of TEUL and evidence of
petrochemical and chemical operations, natural gas liquids extraction
mineralogical changes during their early life cycle in process operation.
plants, natural gas liquefaction plants, and other onshore facilities covered
Pages: 28
by the OSHA Process Safety Management of Highly Hazardous Chemicals,
1st Edition | March 2021 | Product Number: C98101 | Price: $88.00
29 CFR 1910.119.
Buildings covered by this RP are rigid structures intended for permanent use
PETROLEUM PRODUCTS AND PETROLEUM PRODUCT SURVEYS
in fixed locations. Tents, fabric enclosures and other soft-sided structures are
outside the scope of this document. This 3rd Edition of RP 752:2009
API/NPRA Survey
supersedes all previous editions, including the technical data provided in
Final Report: 1996 API/NPRA Survey of Refining Operations and
those documents.
Product Quality
Significant research and development of technology pertinent to building
siting evaluations has been performed since the publication of the previous
A survey of industry refining data for the period May 1 through August 31,
editions of RP 752. Examples of updated technology include prediction of
1996. The report includes information on domestically produced gasoline
blast damage to buildings, determination of occupant vulnerabilities, and
and diesel product quality as well as aggregate domestic refining capacity
estimates of event frequencies. Prior versions of RP 752 and the technical
and average operating data. Pages: 190
data included in them should not be used for building siting evaluations. The
1st Edition | July 1997 | Product Number: F10001 | Price: $67.00
2nd Edition of RP 752 covered all building types both permanent and
Aviation Turbines Fuels, 2001 | Price: $96.00
portable. This 3rd Edition of RP 752 does not cover portable buildings.
Heating Oils, 2002 | Price: $106.00
Portable buildings are now covered by RP 753. It is recognized, however, that
Motor Gasolines, Winter 2001-2002 | Price: $128.00
portable buildings specifically designed for significant blast load represent a
Motor Gasolines, Summer 2001 | Price: $128.00
potential area of overlap between RP 753 and RP 752. In accordance with
1.3 of this document:
Diesel Fuel Oils, 2002 | Price: $106.00
“Buildings described in API RP 753, Management of Hazards
Magnetic computer tapes of raw data are available upon request. Reports
Associated with Location of Process Plant Portable Buildings, First
from previous years are also available.
Edition, June 2007, as ‘portable buildings specifically designed to
Order these petroleum product surveys from:
resist significant blast loads’ and intended for permanent use in a fixed
TRW Petroleum Technologies
location are covered in this document (API RP 752). All other portable
P.O. Box 2543 | Bartlesville, OK 74005
buildings are covered by API RP 753.” Pages: 27
Attn: Cheryl Dickenson
3rd Edition | December 2009 | Reaffirmed: August 2020
918-338-4419
Product Number: K75203 | Price: $153.00
120
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RP 753
safety-sensitive decisions. On-site contractors involved in process safety-
Management of Hazards Associated with Location of Process Plant
sensitive actions shall have fatigue risk management systems equivalent to
the criteria outlined in this document. Pages: 17
Portable Buildings
2nd Edition | May 2019 | Product Number: K75502 | Price: $145.00
Provides guidance for reducing the risk to personnel located in portable
buildings from potential explosion, fire and toxic release hazards. While
TR 755-1
occupied permanent buildings (e.g. control rooms, operator shelters)
Technical Support Document for ANSI/API RP 755, Fatigue Risk
located near covered process area are typically constructed to be blast and
fire resistant, conventional portable buildings (i.e. light wood trailers) are
Management Systems for Personnel in the Refining and
typically not constructed to be blast and fire resistant. Past explosion
Petrochemical Industries
accidents have demonstrated that occupants of conventional portable
Identifies and explains the scientific and operational issues considered
buildings are susceptible to injuries from structural failures, building
during the preparation of RP 755. By providing the reasoning behind the
collapse, and building debris and projectiles.
specific wording in the RP 755 document, this document supports each key
statement in RP 755 in sequence so that it can be used in parallel with the
Guidance is provided based on the following principles.
RP 755 text. To make this document accessible and manageable, key
Locate personnel away from covered process areas consistent with safe
scientific sources and references are provided to help readers gain access to
and effective operations.
the scientific literature.
Minimize the use of occupied portable buildings in close proximity to
Fatigue Risk Management Systems (FRMS) have emerged and been widely
covered process areas.
recognized as a more effective approach to managing and mitigating
Manage the occupancy of portable building especially during periods of
employee fatigue risk in the 24/7 workplace. The core feature of the FRMS is
increased risk including unit start up or planned shut-down operations.
that it is a data-driven, risk-informed, safety performance-based system. The
FRMS implementation process first identifies all sources of fatigue risk in the
Design, construct, install, and maintain occupied portable buildings to
business operation, then introduces mitigating policies, technologies, and
protect occupants against potential hazards.
procedures to reduce the risk, and most importantly then maintains them in
Manage the use of portable buildings as an integral part of the design,
a proactively managed continuous improvement system. The history of FRMS
construction, and maintenance operation of a facility. Pages: 22
was recently summarized.
1st Edition | June 2007 | Reaffirmed: August 2020
This method represents a significant step change from the traditional
Product Number: K75301 | Price: $153.00
approaches of either relying on maximum limits to hours of work or minimum
limits to hours of rest (variously called Hours of Service, Work-Rest Rules,
Working Time Directives), or adopting intermittent or piece-meal solutions
RP 754
(e.g. a fatigue training program or a shift schedule redesign), depending on
Process Safety Performance Indicators for the Refining and
the interests and initiative of local site managers.
Petrochemical Industries
One essential feature of FRMS is that it is a system meant to be improved
(ANSI/API RP 754)
upon on a regular and continuous basis. It is not a set of guidelines
Identifies leading and lagging process safety indicators useful for driving
designed for one-time compliance but instead provides a framework that will
performance improvement. As a framework for measuring activity, status, or
evolve over time, driven by the collection of data on fatigue risk and fatigue
performance, this document classifies process safety indicators into four
outcomes (e.g. fatigue-related incidents). Pages: 49
tiers of leading and lagging indicators. Tiers 1 and 2 are suitable for
1st Edition | April 2010 | Product Number: K755101 | Price: $112.00
nationwide public reporting and Tiers 3 and 4 are intended for internal use
at individual facilities. Guidance on methods for development and use of
RP 756
performance indicators is also provided. This RP was developed for the
Management of Hazards Associated with Location of Process Plant
refining and petrochemical industries, but may also be applicable to other
industries with operating systems and processes where loss of containment
Tents
has the potential to cause harm. Applicability is not limited to those facilities
Provides guidance for managing the risk from explosions, fires and toxic
covered by the OSHA Process Safety Management Standard, 29 CFR
material releases to on-site personnel located in tents. The term “tent” is
1910.119, or similar national and international regulations. Pages: 134
used to describe a wide range of structures and is defined in §3.15. This RP
3rd Edition | August 2021 | Product Number: K75403 | Price: $182.00
was developed for use at refineries, petrochemical and chemical operations,
natural gas liquids extraction plants, natural gas liquefaction plants, and
RP 755
other onshore facilities covered by OSHA 29 CFR 1910.119.
Fatigue Risk Management Systems for Personnel in the Refining and
The focus of this RP is primarily on process related hazards. However, non-
process related hazards may exist which could present risks to tent
Petrochemical Industries
occupants. Previous accidents have demonstrated that tent occupants are
(ANSI/API RP 755)
susceptible to injuries from fires originating inside the tent, from tent
Provides guidance to all stakeholders (e.g. employees, managers,
collapse due to extreme weather, and from falling objects. Some of these
supervisors) on understanding, recognizing, and managing employee fatigue
hazards are addressed by tent design standards, manufacturer’s
in the workplace. Should sites decide to use this document, the owners/
recommendations, and local regulations. Pages: 25
operators shall establish policies and procedures to meet the purpose of this
1st Edition| September 2014 | Reaffirmed: August 2020
recommended practice.
Product Number: C75601 | Price: $136.00
This document was developed for refineries, petrochemical and chemical
operations, natural gas liquefaction plants, and other facilities such as those
covered by the OSHA Process Safety Management Standard, 29 CFR
1910.119. This document is intended to apply to a workforce that is
commuting daily to a job location.
ANSI/API RP 755 applies to all employees working night shifts, rotating
shifts, extended hours/days, or call outs who are involved in process safety-
sensitive actions. It should also be considered for others making process
This publication is a new entry in this catalog.
This publication is related to an API licensing, certification, or accreditation program.
121
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TR 756-1
exclusively from wheeled vehicles (i.e. tank trucks or railroad tank cars); and
tanks covered by OSHA 29 CFR 1910.119 and EPA 40 CFR 68, or similar
Process Plant Tent Responses to Vapor Cloud Explosions-Results of
regulations. Pages: 75
the American Petroleum Institute Tent Testing Program
5th Edition | September 2020
Beginning in 2011, the American Petroleum Institute (API) to performed
Product Number: K235005 | Price: $135.00
vapor cloud explosion (VCE) tests to determine the response of tents to the
potential explosion hazards that may be present at refineries, petrochemical
and chemical operations, natural gas and other onshore process facilities
HEALTH, ENVIRONMENT, AND SAFETY: SOIL AND GROUNDWATER
covered by OSHA 29 CFR 1910.119. The testing was conducted to provide
data for use by the API committee developing RP 756. This publication, TR
Publ 422
756-1, contains information on the results of the API tent testing program.
Groundwater Protection Programs for Petroleum Refining and
Pages: 597
Storage Facilities: A Guidance Document
1st Edition|September 2014|Product Number: C756101|Price: $206.00
Reflects continuing industry action and commitment to positively address
groundwater protection by developing and implementing individual
HEALTH, ENVIRONMENT, AND SAFETY: GENERAL
groundwater protection plans. Provides additional guidance to help
petroleum facilities identify the types of issues that may need to be
Cumulative Impact of Environmental Regulations on the U.S.
addressed in a groundwater protection plan. Intended to help refineries,
Petroleum Refining, Transportation and Marketing Industries
terminals associated with transportation pipelines, product distribution
terminals, and other downstream petroleum storage units develop
1st Edition | Product Number: C00015 | available at https://www.api.org
groundwater protection plans that are tailored to their individual
circumstances. Pages: 9
RP 751
1st Edition | October 1994 | Product Number: C42201 | Price: $71.00
Safe Operation of Hydrofluoric Acid Alkylation Units
Provides requirements (shall) and recommendations (should) for practices
Publ 800
and procedures related to safety, operations, design, inspection, and
Literature Survey: Subsurface and Groundwater Protection Related
maintenance to support the safe and reliable operation of hydrofluoric acid
(HF) alkylation units. Topics include hazard management; operating
to Petroleum Refinery Operations
procedures and worker protection; materials, construction, inspection, and
This report is the principal product of an API-sponsored project to prepare a
work practices; transportation and inventory control; pressure-relief, product
background basis for the development of further information on subsurface
treatment, and utility systems; and risk mitigation. This document contains
and groundwater protection at refineries. It contains an explanation of how
requirements and recommendations that have been found effective based
the literature survey was conducted; annotations for pertinent articles; a
on broad industry acceptance, proven effective industry practices, testing,
discussion of applicable federal statutes and regulations; and annotations
and regulatory requirements. Pages: 181
for pertinent regulatory programs under the 5 principal statutes that apply to
5th Edition | August 2021 | Product Number: K75105 | Price: $194.00
refinery operations. Pages: 145
1st Edition | September 1988 | Product Number: C80000 | Price: $100.00
Std 2350
Overfill Protection for Storage Tanks in Petroleum Facilities
SECURITY
(includes Errata 1 dated April 2021)
(ANSI/API Std 2350))
Std 780
Applies to storage tanks associated with marketing, refining, pipeline, and
Security Risk Assessment Methodology for the Petroleum and
terminals operations and with tanks containing Class I or Class II petroleum
Petrochemical Industries
liquids and use is recommended for Class III petroleum liquids. This
standard addresses overfill protection for petroleum storage tanks. It
Prepared by a Security Risk Assessment (SRA) Committee of the American
recognizes that prevention provides the most basic level of protection, thus
Petroleum Institute (API) to assist the petroleum and petrochemical
while using both terms “protection” and “prevention,” the document
industries in understanding security risk assessment and in conducting
emphasizes prevention. The standard's scope covers overfill (and damage)
SRAs. The standard describes the recommended approach for assessing
prevention practices for aboveground storage tanks in petroleum facilities,
security risk widely applicable to the types of facilities operated by the
including refineries, marketing terminals, bulk plants, and pipeline terminals
industry and the security issues the industry faces. The standard is intended
that receive flammable and combustible liquids. The fourth edition continues
for those responsible for conducting security risk assessments and
to build on experience and new technology through the use of management
managing security at these facilities. The method described in this standard
systems. Since operations are the primary overfill prevention safeguard, new
is widely applicable to a full spectrum of security issues from theft to insider
definitions and requirements are established for alarms. Risk reduction is
sabotage to terrorism. The API SRA Methodology was developed for the
also addressed by current and generally accepted industry practices.
petroleum and petrochemical industry, for a broad variety of both fixed and
The essential elements of this document are based on current industry safe
mobile applications. This recommended practice describes a single
operating practices and existing consensus standards. Federal, state, and
methodology, rather than a general framework for SRAs, but the
local regulations or laws may contain additional requirements for tank overfill
methodology is flexible and adaptable to the needs of the user. This
protection programs. For existing facilities, the results of a risk-based
methodology constitutes one approach for assessing security vulnerabilities
analysis of aboveground atmospheric petroleum storage tanks may indicate
at petroleum and petrochemical industry facilities. However, there are other
the need for more protection against overfilling. In such cases, some
risk assessment techniques and methods available to industry, all of which
provisions from this standard may be suitable.
share common risk assessment elements. Pages: 113
1st Edition | May 2013 | Reaffirmed: February 2022
The purpose of this standard is to assist owner/operators and operating
personnel in the prevention of tank overfills by implementation of a
Product Number: K78001 | Price: $206.00
comprehensive overfill prevention process (OPP). The goal is to receive
product into the intended storage tank without overfill or loss of containment.
This standard does not apply to: underground storage tanks; aboveground
tanks of 1320 U.S. gallons (5000 liters) or less; aboveground tanks which
comply with PEI 600; pressure vessels; tanks containing non-petroleum
liquids; tanks storing LPG and LNG; tanks at service stations; tanks filled
122
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Refining
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RP 781
Facility Security Plan Methodology for the Oil and Natural Gas
Industries
Provides the framework to establish a secure workplace. The plan provides
an overview of the threats facing the facility and describes the security
measures and procedures designed to mitigate risk and protect people,
assets, operations, and company reputation. This API standard was
prepared with guidance and direction from the API Security Committee, to
assist the petroleum and petrochemical industries in the preparation of a
Facility Security Plan (FSP). This standard specifies the requirements for
preparing an FSP as well as a discussion of the typical elements included in
an FSP.
This standard is intended to be flexible and adaptable to the needs of the
user. It is noted that the content of an FSP can vary depending on
circumstances such as facility size, location, and operations. This
methodology is one approach for preparing an FSP at petroleum and
petrochemical facilities. There are other security plan formats available for
the industry. It is the responsibility of the user to choose the format and
content of the FSP that best meets the needs of a specific facility. The format
and content of some FSPs should be dictated by government regulations for
covered facilities. This standard is not intended to supersede the
requirements of any regulated facility but may be used as a reference
document. Pages: 82
1st Edition | September 2016 | Product Number: K78101 | Price: $157.00
This publication is a new entry in this catalog.
This publication is related to an API licensing, certification, or accreditation program.
123
Safety and Fire Protection
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RP 54
Occupational Safety and Health for Oil and Gas Well Drilling and
Servicing Operations
UPSTREAM SAFETY STANDARDS
(includes Addendum 1 dated June 2021)
Recommends practices and procedures for promoting and maintaining safe
RP 49
and healthy working conditions for personnel in drilling and well servicing
Recommended Practice for Drilling and Well Servicing Operations
operations. These recommendations apply to rotary drilling rigs, well
Involving Hydrogen Sulfide
servicing rigs, and special services as they relate to operations on location. It
is intended that the applicable requirements and recommendations of some
Provides recommendations that apply to oil and gas well drilling and
sections of the standard be applied, as appropriate, to other sections. The
servicing operations involving hydrogen sulfide. These operations include well
recommendations are not intended to cover seismic drilling or water well
drilling, completion, servicing, workover, downhole maintenance, and plug
drilling operations. These recommendations do not apply to site preparation
and abandonment procedures conducted with hydrogen sulfide present in
and site remediation operations. Pages: 62
the fluids being handled. Coverage of this publication is applicable to
4th Edition | February 2019 | Product Number: G54004 | Price: $140.00
operations confined to the original wellbore or original total depth and
applies to the selection of materials for installation or use in the well and in
RP 55
the well drilling or servicing operation(s). The presence of hydrogen sulfide in
Recommended Practice for Oil and Gas Producing and Gas
these operations also presents the possibility of exposure to sulfur dioxide
Processing Plant Operations Involving Hydrogen Sulfide
from the combustion of hydrogen sulfide. Pages: 29
Covers recommendations for protection of employees and the public, as well
3rd Edition | May 2001 | Reaffirmed: January 2013
as conducting oil and gas producing and gas processing plant operations
Product Number: G49003 | Price: $96.00
where hydrogen sulfide is present in the fluids being produced. Pages: 40
2nd Edition | February 1995 | Reaffirmed: January 2013
RP 49 *
Product Number: G55002 | Price: $124.00
Recommended Practice for Drilling and Well Servicing Operations
Involving Hydrogen Sulfide-Kazakh
Std 65-2
Kazakh translation of RP 49.
Isolating Potential Flow Zones During Well Construction
3rd Edition | May 2001 | Reaffirmed: January 2013
Contains best practices for zone isolation in wells to prevent annular
Product Number: G4903K | Price: $96.00
pressure and/or flow through or past pressure-containment barriers that are
installed and verified during well construction. Well construction practices
RP 49 *
that may affect barrier sealing performance are mentioned along with
Recommended Practice for Drilling and Well Servicing Operations
methods to help ensure positive effects or to minimize any negative ones.
The objectives of this guideline are two-fold. The first is to help prevent and/
Involving Hydrogen Sulfide-Russian
or control flows just prior to, during, and after primary cementing operations
Russian translation of RP 49.
to install or “set” casing and liner pipe strings in wells. The second objective
3rd Edition | May 2001 | Reaffirmed: January 2013
is to help prevent sustained casing pressure (SCP). The guidance from this
Product Number: G04903R | Price: $96.00
document covers recommendations for pressure-containment barrier design
and installation and well construction practices that affect the zone isolation
process to prevent or mitigate annular fluid flow or pressure. Pages: 83
RP 51R
Environmental Protection for Onshore Oil and Gas Production
2nd Edition | December 2010 | Reaffirmed: November 2016
Product Number: G65202 | Price: $141.00
Operations and Leases
You may download a PDF of this document from https://www.api.org/oil-and-
Provides environmentally sound practices, including reclamation guidelines,
natural-gas/wells-to-consumer/exploration-and-production/hydraulic-
for domestic onshore oil and gas production operations. It is intended to be
applicable to contractors as well as operators. Facilities within the scope of
fracturing/65-2-isolating-potential-flow-zones
this document include all production facilities, including produced water
handling facilities. Offshore and arctic areas are beyond the scope of this
RP 65-3
document. Operational coverage begins with the design and construction of
Wellbore Plugging and Abandonment
access roads and well locations and includes reclamation, abandonment,
Provides guidance for the design, placement, and verification of cement
and restoration operations. Gas compression for transmission purposes or
plugs in wells to be temporarily or permanently abandoned, as well as
production operations, such as gas lift, pressure maintenance, or enhanced
remediation and verification of annular barriers. Wells temporarily
oil recovery (EOR), is included. Annex A provides guidance for a company to
abandoned (suspended) are intended to be re-entered in the future. The
consider as a “good neighbor.” Pages: 35
placement of barriers may depend on whether the well is to be temporarily or
1st Edition | July 2009 | Reaffirmed: December 2015
permanently abandoned. Cement plug lengths are not considered in this
document. Pages: 52
Product Number: G51R01 | Price: $82.00
1st Edition | June 2021 | Product Number: G65301 | Price: $112.00
You may download a PDF of this document from https://www.api.org/oil-
and-natural-gas/wells-to-consumer/exploration-and-production/hydraulic-
fracturing/rp-51r-environmental-protection
*These translated versions are provided for the convenience of our customers and are not officially endorsed by API. The translated versions shall neither replace nor supersede
the English-language versions, which remain the official standards. API shall not be responsible for any discrepancies or interpretations of these translations. Translations may not
include any addenda or errata to the document. Please check the English-language versions for any updates to the documents.
This publication is a new entry in this catalog.
This publication is related to an API licensing, certification, or accreditation program.
125
Safety and Fire Protection
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RP 67
RP 76
Recommended Practice for Oilfield Explosives Safety
Contractor Safety Management for Oil and Gas Drilling and
Applicable to chemical explosives used as an energy source to do work in
Production Operations
oil- and gas-producing operations, and more specifically to explosives
Intended to assist operators, contractors, and subcontractors (third parties)
intended for use inside a wellbore. The purpose of this recommended
in the implementation of a contractor safety program and improve the overall
practice (RP) is primarily to prevent the inadvertent initiation of these
safety performance while preserving the independent contractor relationship.
explosives at the wellsite but also includes some recommendations for safe
It is intended for the Upstream Segment of the petroleum industry; however,
and secure storage and transportation and handling, as well as
since the operator requirements and the contracted work are diverse, this
requirements for design and manufacture of selected equipment.
publication may not be applicable to all operations at each company or to
While some chemicals intended for various nonexplosive applications can
all contract work performed in those operations. Many oil and gas
prove explosive when misused (such as lithium batteries), it is not the intent
exploration and production companies contract for equipment and
of this RP to address these materials. Pages: 85
personnel services for a wide range of activities, including drilling production,
well servicing, equipment repair, maintenance, and construction. Certain
3rd Edition | October 2019 | Product Number: G06703 | Price: $121.00
activities of contractors have the potential to take place either contractor
and/or operator personnel and/or equipment at risk. It is important that
RP 74
operations are carried out in a safe manner. Operators and contractors need
Recommended Practice for Occupational Safety for Onshore Oil and
to provide safe work places and to protect the safety of their work places and
Gas Production Operation
to protect the safety of their workforces and the general public. When they
Recommends practices and procedures for promoting and maintaining safe
work together to improve safety, both benefit. Pages: 60
working conditions for personnel engaged in onshore oil and gas production
2nd Edition | November 2007 | Reaffirmed: January 2013
operations, including special services. Pages: 23
Product Number: G07602 | Price: $62.00
1st Edition | October 2001 | Reaffirmed: January 2013
Product Number: G74001 | Price: $67.00
MULTI-SEGMENT PUBLICATIONS
RP 75
Firefighting Foam Transition Guidance
Safety and Environmental Management System for Offshore
Provides the industry with suggestions and considerations for the transition
Operations and Assets
from C8 legacy fluorinated foams concentrates to another type of foam
Provides companies engaged in offshore operations with a framework for the
concentrate [such as C6 or synthetic fluorine-free foam (SFFF)]. For each
establishment, implementation, and maintenance of a Safety and
step of the MOC, a separate document is available that provides
Environmental Management System (SEMS) to manage and reduce risks
considerations and examples on how an entity may choose to execute the
associated with safety and the environment to prevent incidents and events.
transition. While it is ideal to have a drop-in foam concentrate replacement
This recommended practice applies, in part or whole, to companies engaged
with minimum changes in processes or practices to use during this
in offshore operations, from lease evaluation through decommissioning.
transition, the MOC process plans for any changes that must be accounted
This document is not intended to be prescriptive or limiting on the
for. Pages: 32
expectations of each SEMS element; rather, it allows flexibility appropriate to
October 2020 | To obtain a copy of this report, please visit
the size, scope, and risk of a Company's assets and operations. It is advised
that users of this document review and comply with applicable legal and
fighting-Foam-Transition-Guidance-October-2020.pdf
regulatory requirements, and conform with applicable industry codes and
standards.
RP 752
Consideration may be given to using this document to help systematically
Management of Hazards Associated with Location of Process Plant
manage other aspects of operations, such as security and health. Pages: 34
Permanent Buildings
4th Edition | December 2019 | Product Number: G07504 | Price: $110.00
Provides guidance for managing the risk from explosions, fires and toxic
material releases to on-site personnel located in new and existing buildings
Bull 75L
intended for occupancy. This RP was developed for use at refineries,
Guidance Document for the Development of a Safety and
petrochemical and chemical operations, natural gas liquids extraction
Environmental Management System for Onshore Oil and Natural
plants, natural gas liquefaction plants, and other onshore facilities covered
Gas Production Operations and Associated Activities
by the OSHA Process Safety Management of Highly Hazardous Chemicals,
Provides general information and guidance for the development of a safety
29 CFR 1910.119.
and environmental management system (SEMS) for onshore oil and natural
Buildings covered by this RP are rigid structures intended for permanent use
gas operations, including drilling, production, and well servicing activities.
in fixed locations. Tents, fabric enclosures and other soft-sided structures are
Although there is an extensive amount of information that has been
outside the scope of this document. This 3rd Edition of RP 752:2009
developed on the topic of safety and environmental management systems,
supersedes all previous editions, including the technical data provided in
this document focuses on this industry sector to help foster continuous
those documents.
improvement in our industry’s safety and environmental performance. It is
recognized that many onshore oil and natural gas companies have effective
Significant research and development of technology pertinent to building
SEMS in place; however, the intent of this document is to provide an
siting evaluations has been performed since the publication of the previous
additional tool that can assist these and especially other operators in taking
editions of RP 752. Examples of updated technology include prediction of
the next step toward implementing a complete system at a pace that
blast damage to buildings, determination of occupant vulnerabilities, and
complements their business plan. For those who already have a mature
estimates of event frequencies. Prior versions of RP 752 and the technical
SEMS in place, this document can be used for continuous improvement of
data included in them should not be used for building siting evaluations. The
the system. Pages: 12
2nd Edition of RP 752 covered all building types both permanent and
1st Edition | November 2007 | Product Number: G75L01 | Price: $37.00
portable. This 3rd Edition of RP 752 does not cover portable buildings.
Portable buildings are now covered by RP 753. It is recognized, however, that
126
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portable buildings specifically designed for significant blast load represent a
RP 755
potential area of overlap between RP 753 and RP 752. In accordance with
Fatigue Risk Management Systems for Personnel in the Refining and
1.3 of this document:
Petrochemical Industries
“Buildings described in API RP 753, Management of Hazards Associated
(ANSI/API RP 755)
with Location of Process Plant Portable Buildings, First Edition, June 2007,
Provides guidance to all stakeholders (e.g. employees, managers,
as ‘portable buildings specifically designed to resist significant blast loads’
supervisors) on understanding, recognizing, and managing employee fatigue
and intended for permanent use in a fixed location are covered in this
in the workplace. Should sites decide to use this document, the owners/
document (API RP 752). All other portable buildings are covered by API RP
operators shall establish policies and procedures to meet the purpose of this
753.” Pages: 27
recommended practice.
3rd Edition | December 2009 | Reaffirmed: August 2020
This document was developed for refineries, petrochemical and chemical
Product Number: K75203 | Price: $153.00
operations, natural gas liquefaction plants, and other facilities such as those
covered by the OSHA Process Safety Management Standard, 29 CFR
RP 753
1910.119. This document is intended to apply to a workforce that is
Management of Hazards Associated with Location of Process Plant
commuting daily to a job location.
Portable Buildings
ANSI/API RP 755 applies to all employees working night shifts, rotating
Provides guidance for reducing the risk to personnel located in portable
shifts, extended hours/days, or call outs who are involved in process safety-
buildings from potential explosion, fire and toxic release hazards. While
sensitive actions. It should also be considered for others making process
occupied permanent buildings (e.g. control rooms, operator shelters)
safety-sensitive decisions. On-site contractors involved in process safety-
located near covered process area are typically constructed to be blast and
sensitive actions shall have fatigue risk management systems equivalent to
fire resistant, conventional portable buildings (i.e. light wood trailers) are
the criteria outlined in this document. Pages: 17
typically not constructed to be blast and fire resistant. Past explosion
2nd Edition | May 2019 | Product Number: K75502 | Price: $145.00
accidents have demonstrated that occupants of conventional portable
buildings are susceptible to injuries from structural failures, building
collapse, and building debris and projectiles.
TR 755-1
Technical Support Document for ANSI/API RP 755, Fatigue Risk
Guidance is provided based on the following principles.
Management Systems for Personnel in the Refining and
Locate personnel away from covered process areas consistent with safe
Petrochemical Industries
and effective operations.
Identifies and explains the scientific and operational issues considered
Minimize the use of occupied portable buildings in close proximity to
during the preparation of RP 755. By providing the reasoning behind the
covered process areas.
specific wording in the RP 755 document, this document supports each key
Manage the occupancy of portable building especially during periods of
statement in RP 755 in sequence so that it can be used in parallel with the
increased risk including unit start up or planned shut-down operations.
RP 755 text. To make this document accessible and manageable, key
Design, construct, install, and maintain occupied portable buildings to
scientific sources and references are provided to help readers gain access to
protect occupants against potential hazards.
the scientific literature.
Manage the use of portable buildings as an integral part of the design,
Fatigue Risk Management Systems (FRMS) have emerged and been widely
construction, and maintenance operation of a facility. Pages: 22
recognized as a more effective approach to managing and mitigating
1st Edition | June 2007 | Reaffirmed: August 2020
employee fatigue risk in the 24/7 workplace. The core feature of the FRMS is
Product Number: K75301 | Price: $153.00
that it is a data-driven, risk-informed, safety performance-based system. The
FRMS implementation process first identifies all sources of fatigue risk in the
RP 754
business operation, then introduces mitigating policies, technologies, and
Process Safety Performance Indicators for the Refining and
procedures to reduce the risk, and most importantly then maintains them in
Petrochemical Industries
a proactively managed continuous improvement system. The history of FRMS
(ANSI/API RP 754)
was recently summarized.
Identifies leading and lagging process safety indicators useful for driving
This method represents a significant step change from the traditional
performance improvement. As a framework for measuring activity, status, or
approaches of either relying on maximum limits to hours of work or minimum
performance, this document classifies process safety indicators into four
limits to hours of rest (variously called Hours of Service, Work-Rest Rules,
tiers of leading and lagging indicators. Tiers 1 and 2 are suitable for
Working Time Directives), or adopting intermittent or piece-meal solutions
nationwide public reporting and Tiers 3 and 4 are intended for internal use
(e.g. a fatigue training program or a shift schedule redesign), depending on
at individual facilities. Guidance on methods for development and use of
the interests and initiative of local site managers.
performance indicators is also provided. This RP was developed for the
refining and petrochemical industries, but may also be applicable to other
One essential feature of FRMS is that it is a system meant to be improved
industries with operating systems and processes where loss of containment
upon on a regular and continuous basis. It is not a set of guidelines
has the potential to cause harm. Applicability is not limited to those facilities
designed for one-time compliance but instead provides a framework that will
covered by the OSHA Process Safety Management Standard, 29 CFR
evolve over time, driven by the collection of data on fatigue risk and fatigue
1910.119, or similar national and international regulations. Pages: 134
outcomes (e.g. fatigue-related incidents). Pages: 49
3rd Edition | August 2021 | Product Number: K75403 | Price: $182.00
1st Edition | April 2010 | Product Number: K755101 | Price: $112.00
This publication is a new entry in this catalog.
This publication is related to an API licensing, certification, or accreditation program.
127
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RP 756
at petroleum and petrochemical industry facilities. However, there are other
risk assessment techniques and methods available to industry, all of which
Management of Hazards Associated with Location of Process Plant
share common risk assessment elements. Pages: 113
Tents
1st Edition | May 2013 | Reaffirmed: February 2022
Provides guidance for managing the risk from explosions, fires and toxic
Product Number: K78001 | Price: $206.00
material releases to on-site personnel located in tents. The term “tent” is
used to describe a wide range of structures and is defined in §3.15. This RP
RP 2001
was developed for use at refineries, petrochemical and chemical operations,
Fire Protection in Refineries
natural gas liquids extraction plants, natural gas liquefaction plants, and
other onshore facilities covered by OSHA 29 CFR 1910.119. The focus of
Provides a better understanding of refinery fire protection and the steps
this RP is primarily on process related hazards. However, non-process related
needed to promote the safe storage, handling, and processing of petroleum
and petroleum products in refineries. A basic premise of this standard is that
hazards may exist that could present risks to tent occupants. Previous
fire prevention provides the fundamental foundation for fire protection.
accidents have demonstrated that tent occupants are susceptible to injuries
from fires originating inside the tent, from tent collapse due to extreme
This publication covers basic concepts of refinery fire protection. It reviews
weather, and from falling objects. Some of these hazards are addressed by
the chemistry and physics of refinery fires; discusses how the design of
tent design standards, manufacturer’s recommendations, and local
refinery systems and infrastructure impact the probability and consequences
regulations. Pages: 25
of potential fires; describes fire control and extinguishing systems typically
used in refineries; examines fire protection concepts that should be covered
1st Edition | September 2014 | Reaffirmed: August 2020
in operating and maintenance practices and procedures; and provides
Product Number: C75601 | Price: $136.00
information on organization and training for refinery emergency responders.
Many of the concepts, systems, and equipment discussed in this document
TR 756-1
are covered in detail in referenced publications, standards, or governmental
Process Plant Tent Responses to Vapor Cloud Explosions-Results of
requirements. Pages: 90
the American Petroleum Institute Tent Testing Program
10th Edition | July 2019 | Product Number: C200110 | Price: $180.00
Beginning in 2011, the American Petroleum Institute (API) to performed
vapor cloud explosion (VCE) tests to determine the response of tents to the
RP 2003
potential explosion hazards that may be present at refineries, petrochemical
Protection Against Ignitions Arising Out of Static, Lightning, and
and chemical operations, natural gas and other onshore process facilities
Stray Currents
covered by OSHA 29 CFR 1910.119. The testing was conducted to provide
data for use by the API committee developing RP 756. This publication, TR
Presents the current state of knowledge and technology in the fields of static
756-1, contains information on the results of the API tent testing program.
electricity, and stray currents applicable to the prevention of hydrocarbon
Pages: 597
ignition in the petroleum industry and is based on both scientific research
and practical experience. The principles discussed in this recommended
1st Edition|September 2014| Product Number: C756101|Price: $206.00
practice are applicable to other operations where ignitable liquids and gases
are handled. Their use should lead to improved safety practices and
Publ 770
evaluations of existing installations and procedures. Pages: 76
A Manager's Guide to Reducing Human Errors-Improving Human
8th Edition | September 2015 | Reaffirmed: March 2020
Performance in the Process Industries
Product Number: K20038 | Price: $206.00
Intended for an audience of middle managers to senior executives who have
different levels of knowledge about human factors engineering. It is designed
RP 2009
to equip them with a basic understanding of the causes of human errors and
Safe Welding, Cutting, and Hot Work Practices in the Petroleum and
to suggest ways for reducing human errors at individual facilities. It also
Petrochemical Industries
describes how to incorporate human reliability analysis (HRA) into process
safety management activities. Pages: 85
Provides information to assist in the safe performance of welding, cutting,
and other hot work activities to be done safely in petroleum and
1st Edition | March 2001 | Product Number: K77001 | Price: $82.00
petrochemical operations. The understanding of potential hazards, and
application of this knowledge, can help reduce the probability and severity of
Std 780
incidents and the risk of harmful health effects from those activities.
Security Risk Assessment Methodology for the Petroleum and
Personnel engaged in hot work should have a comprehensive understanding
Petrochemical Industries
of the potential hazards associated with the activity and materials involved.
Prepared by a Security Risk Assessment (SRA) Committee of the American
RP 2009 was updated to include added precautions to prevent fires and
Petroleum Institute (API) to assist the petroleum and petrochemical
incidents during welding operations, as well as an awareness of the hazards
industries in understanding security risk assessment and in conducting
of inhalation of welding fumes. Additionally, it includes specific guidance to
SRAs. The standard describes the recommended approach for assessing
evaluate procedures for certain types of work equipment in service, supports
security risk widely applicable to the types of facilities operated by the
UN Sustainable Development Goal #9 for Resilient Infrastructure, and is
industry and the security issues the industry faces. The standard is intended
included in the U.S. Department of Labor OSHA’s resources materials for
for those responsible for conducting security risk assessments and
Process Safety Management. Pages: 43
managing security at these facilities. The method described in this standard
8th Edition | March 2022 | Product Number: K20098 | Price: $105.00
is widely applicable to a full spectrum of security issues from theft to insider
sabotage to terrorism. The API SRA Methodology was developed for the
petroleum and petrochemical industry, for a broad variety of both fixed and
mobile applications. This recommended practice describes a single
methodology, rather than a general framework for SRAs, but the
methodology is flexible and adaptable to the needs of the user. This
methodology constitutes one approach for assessing security vulnerabilities
128
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RP 2027
RP 2217A
Ignition Hazards and Safe Work Practices for Abrasive Blasting of
Safe Work in Inert Confined Spaces in the Petroleum and
Atmospheric Storage Tanks in Hydrocarbon Service
Petrochemical Industries
Provides safe work practices for the prevention and control of vapor, ignition,
Covers design, materials, face-to-face dimensions, pressure-temperature
and other potential hazards during abrasive blasting of aboveground storage
ratings, and examination, inspection, and test requirements for two types of
tanks in liquid hydrocarbon service at atmospheric pressure. It also provides
check valves:
assistance to employers in developing operating procedures that provide for
Type ‘A’ check valves are short face-to-face and can be: wafer, lug, or
hazard recognition to significantly reduce ignition risks during abrasive
double flanged; single plate or dual plate; gray iron, ductile iron, steel,
blasting of hydrocarbon storage tanks in service that may contain or have the
nickel alloy, or other alloy designed for installation between Classes 125
potential to develop a flammable atmosphere in the vapor space. This RP
and 250 cast iron flanges as specified in ASME B16.1, between Classes
applies to safe work practices required for abrasive blasting of exterior shells
150 and 300 ductile iron flanges as specified in ASME B16.42, between
and exterior roofs of all aboveground atmospheric storage tanks in liquid
Classes 150 and 2500 steel flanges as specified in ASME B16.5, and
hydrocarbon service. It also applies to safe work practices for abrasive
between Classes 150 and 600 steel pipeline flanges as specified in MSS
blasting conducted on the roofs and inner portions of the exposed surfaces
SP-44 or steel flanges as specified in ASME B16.47.
of shells (that portion of the shell above the roof level) on open-top
Type ‘B’ bolted cover swing check valves are long face-to-face as defined
(external) floating roof tanks. This RP also covers recognition and control of
in 5.1.2 and can be: flanged or buttwelding ends of steel, nickel alloy, or
ignition hazards that are specific to and may be present during abrasive
other alloy material. End flanges shall be as specified in ASME B16.5 or
blasting of aboveground storage tanks in liquid hydrocarbon service at
ends shall be butt-welding as specified in ASME B16.25. Pages: 34
atmospheric pressure. The ignition sources covered in this RP include static
electricity, internal combustion engines, electric motors, friction sparks, hot
5th Edition | July 2017 | Product Number: K2217A5 | Price: $157.00
metal surfaces, and external-to-the-work ignition sources. Pages: 27
RP 2218
4th Edition | November 2018 | Product Number: C20274 | Price: $132.00
Fireproofing Practices in Petroleum and Petrochemical Processing
RP 2028
Plants
Flame Arresters in Piping Systems
Intended to provide guidance for selecting, applying, and maintaining
fireproofing systems designed to limit the extent of fire-related property loss
Covers the use and limitations of flame arresters installed in piping systems
from pool fires in the petroleum and petrochemical industries. Where
in the petroleum and petrochemical industries. It provides a general overview
comparable hazards exist, and to the extent appropriate, it may be applied
of flame arresters currently in use and some potential concerns or
to other facilities that could experience similar severe fire exposure and
limitations. Applicable combustion and flame propogation parameters are
potential losses.
discussed including the distinction between arresting flames versus arresting
This RP identifies fireproofing needs for petroleum and petrochemical plants
detonations. Pages: 12
specifically focusing on property loss protection for pool fires scenarios in
3rd Edition | February 2002 | Reaffirmed: December 2010
on-shore processing plants. Pages: 60
2-Year Extension: February 2015 | Product Number: K20283 | Price: $65.00
3rd Edition | July 2013 | Reaffirmed: March 2020
Product Number: K22183 | Price: $174.00
RP 2030
Application of Fixed Water Spray Systems for Fire Protection in the
RP 2219
Petroleum and Petrochemical Industries
Safe Operation of Vacuum Trucks Handling Flammable and
Combustible Liquids in Petroleum Service
Provides guidance for the petroleum industry and some petrochemical
industry applications (for non-water-reactive petrochemicals with physical
Provides information concerning the safe operation of vacuum trucks
and combustion characteristics comparable to hydrocarbons) in determining
engaged in all aspects of handling flammable and combustible liquids,
where water spray systems might be used to provide protection from fire
associated waste water, produced water, sour water, basic sediment and
damage for equipment and structures. Pages: 21
water (BS&W), caustics, spent acids, or other fluids stemming from
petroleum operations, products, powders, and the hazard of dust explosions.
4th Edition | September 2014 | Product Number: K20304 | Price: $114.00
This publication discusses the types of vacuum pumps and cargo tanks
associated with vacuum truck operations, the common hazards associated
RP 2201
with those vacuum truck operations, and representative safe work practices
Safe Hot Tapping Practices in the Petroleum and Petrochemical
and precautions to help prevent accidents and injuries. Appendix G provides
Industries
brief descriptions of a variety of incidents involving vacuum trucks, including
offloading into open areas. These may be useful in reviewing specific
Provides information to assist in safely conducting hot tapping operations on
operating procedures or developing materials for safety meetings or pre-job
equipment in service in the petroleum and petrochemical industries. No
briefings. Pages: 60
document can address all situations nor answer all potential questions;
however, the understanding of potential hazards, and application of this
4th Edition | June 2016 | Product Number: K22194 | Price: $179.00
knowledge, can help reduce the probability and severity of incidents. Pages: 27
5th Edition | June 2003 | Reaffirmed: March 2020
Publ 2375
2-Year Extension: February 2015 | Product Number: K22015 | Price: $94.00
1996 Summary of U.S. Occupational Injuries, Illnesses, and
Fatalities in the Petroleum Industry
RP 2210
This annual summary reports on cases recordable in 1996 under the U.S.
Flame Arresters for Vents of Tanks Storing Petroleum Products
Bureau of Labor Statistics’ recordkeeping guidelines. The survey is based on
data submitted to the American Petroleum Institute by 176 oil and gas
Discusses the benefits and detriments associated with the use of flame
arresters on vents utilized on atmospheric fixed-roof tanks. Pages: 4
companies, employing 285,885 persons. The report includes information
regarding injuries, illnesses, fatalities, lost workday cases, and incidence
3rd Edition | June 2000 | Reaffirmed: March 2020
rates by function.
Product Number: K22103 | Price: $71.00
June 1997 | Product Number: K23751 | Price: $104.00
This publication is a new entry in this catalog.
This publication is related to an API licensing, certification, or accreditation program.
129
Safety and Fire Protection
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Publ 2376
Publ 2386
1997 Summary of U.S. Occupational Injuries, Illness, and Fatalities
2007 Survey on Petroleum Industry Occupational Injuries, Illness,
in the Petroleum Industry
and Fatalities Summary Report: Aggregate Data Only
May 2008 | Product Number: K23861 | Price: $112.00
June 1998 | Product Number: K23761 | Price: $104.00
Publ 2387
Publ 2377
2008 Survey on Petroleum Industry Occupational Injuries, Illness,
1998 Summary of U.S. Occupational Injuries, Illness, and Fatalities
and Fatalities Summary Report: Aggregate Data Only
in the Petroleum Industry
March 2009 | Product Number: K23871 | Price: $112.00
March 1999 | Product Number: K23771 | Price: $112.00
Publ 2388
Publ 2378
2009 Survey on Petroleum Industry Occupational Injuries, Illness,
and Fatalities Summary Report: Aggregate Data Only
1999 Survey on Petroleum Industry Occupational Injuries, Illness,
and Fatalities Summary Report: Aggregate Data Only
Reports on cases recordable in 2009 under the U.S. Bureau of Labor Statistics’
recordkeeping guidelines. The survey is based on data submitted to API by oil
June 2000 | Product Number: K23781 | Price: $112.00
and gas companies. The report includes information regarding injuries, illness,
and fatalities, lost workday cases, and incidence rates by function.
Publ 2379
April 2010 | Product Number: K23881 | Price: $112.00
2000 Survey on Petroleum Industry Occupational Injuries, Illness,
and Fatalities Summary Report: Aggregate Data Only
1989 Summary of Occupational Injuries, Illnesses and Fatalities in
March 2001 | Product Number: K23790 | Price: $112.00
the Petroleum Industry
January 1989 | Product Number: K19996 | Price: $64.00
Publ 2380
2001 Survey on Petroleum Industry Occupational Injuries, Illness,
1990 Summary of Occupational Injuries, Illnesses and Fatalities in
and Fatalities Summary Report: Aggregate Data Only
the Petroleum Industry
July 1991 | Product Number: K19988 | Price: $89.00
March 2002 | Product Number: K23801 | Price: $112.00
1991 Summary of Occupational Injuries, Illnesses and Fatalities in
Publ 2381
the Petroleum Industry
2002 Survey on Petroleum Industry Occupational Injuries, Illness,
September 1992 | Product Number: K19987 | Price: $89.00
and Fatalities Summary Report: Aggregate Data Only
June 2003 | Product Number: K23811 | Price: $112.00
1992 Summary of Occupational Injuries, Illnesses and Fatalities in
the Petroleum Industry
Publ 2382
August 1993 | Product Number: K19986 | Price: $89.00
2003 Survey on Petroleum Industry Occupational Injuries, Illness,
and Fatalities Summary Report: Aggregate Data Only
1993 Summary of Occupational Injuries, Illnesses and Fatalities in
the Petroleum Industry
May 2004 | Product Number: K23821 | Price: $112.00
June 1994 | Product Number: K19985 | Price: $104.00
Publ 2383
1994 Summary of U.S. Occupational Injuries, Illnesses and
2004 Survey on Petroleum Industry Occupational Injuries, Illness,
Fatalities in the Petroleum Industry
and Fatalities Summary Report: Aggregate Data Only
June 1995 | Product Number: K19984 | Price: $104.00
March 2005 | Product Number: K23831 | Price: $112.00
1995 Summary of U.S. Occupational Injuries, Illnesses, and
Publ 2384
Fatalities in the Petroleum Industry
2005 Survey on Petroleum Industry Occupational Injuries, Illness,
May 1996 | Product Number: K19983 | Price: $104.00
and Fatalities Summary Report: Aggregate Data Only
This annual summary reports on cases recordable in 2005 under the US
Publ 2510A
Bureau of Labor Statistics’ record keeping guidelines. The survey is based on
Fire Protection Considerations for the Design and Operation of
data submitted to the American Petroleum Institute by oil and gas
companies. The report includes information regarding injuries, illness, and
Liquefied Petroleum Gas (LPG) Storage Facilities
fatalities, lost workday cases, and incidence rates by function.
Supplements Std 2510 and addresses the design, operation, and
May 2006 | Product Number: K23841 | Price: $112.00
maintenance of liquefied petroleum gas (LPG) storage facilities from the
standpoint of prevention and control of releases, fire protection design, and
Publ 2385
fire control measures. The history of LPG storage facility safety experience,
2006 Survey on Petroleum Industry Occupational Injuries, Illness,
facility design philosophy, operating and maintenance procedures, and
various fire protection and fire-fighting approaches are presented. The
and Fatalities Summary Report: Aggregate Data Only
storage facilities covered are LPG installations (storage vessels and
June 2007 | Product Number: K23851 | Price: $112.00
associated loading/unloading/transfer systems) at marine and pipeline
terminals, natural gas processing plants, refineries, petrochemical plants,
and tank farms. Pages: 45
2nd Edition | December 1996 | Reaffirmed: December 2015
Product Number: K2510A | Price: $110.00
130
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This publication is related to an API licensing, certification, or accreditation program.
Safety and Fire Protection
To purchase individual API standards, visit apiwebstore.org
STORAGE TANK SAFETY STANDARDS
Std 2350
Overfill Protection for Storage Tanks in Petroleum Facilities
Std 2015
(includes Errata 1 dated April 2021)
Requirements for Safe Entry and Cleaning of Petroleum Storage Tanks
(ANSI/API Std 2350)
Applicable to stationary atmospheric and low-pressure (up to and including
Applies to storage tanks associated with marketing, refining, pipeline, and
15 psig) aboveground petroleum storage tanks used in all sectors of the
terminals operations and with tanks containing Class I or Class II petroleum
petroleum and petrochemical industry, including crude oil and gas
liquids and use is recommended for Class III petroleum liquids. This
production; refining; petrochemicals; pipelines and terminals; bulk storage;
standard addresses overfill protection for petroleum storage tanks. It
and ethanol facilities. This standard provides requirements for safely
recognizes that prevention provides the most basic level of protection, thus
planning, coordinating, and conducting tank entry and cleaning operations,
while using both terms “protection” and “prevention,” the document
from removal from service through return to service. Pages: 146
emphasizes prevention. The standard's scope covers overfill (and damage)
prevention practices for aboveground storage tanks in petroleum facilities,
8th Edition | January 2018 | Product Number: K20158 | Price: $215.00
including refineries, marketing terminals, bulk plants, and pipeline terminals
that receive flammable and combustible liquids. The fourth edition continues
RP 2021
to build on experience and new technology through the use of management
Management of Atmospheric Storage Tank Fires
systems. Since operations are the primary overfill prevention safeguard, new
Provides experience-based information to enhance the understanding of
definitions and requirements are established for alarms. Risk reduction is
fires in atmospheric storage tanks containing flammable and combustible
also addressed by current and generally accepted industry practices.
materials. It presents a systematic management approach that can assist
The essential elements of this document are based on current industry safe
tank fire prevention. If fires do occur, this information can help responders
operating practices and existing consensus standards. Federal, state, and
optimize fire suppression techniques to reduce the severity of an incident
local regulations or laws may contain additional requirements for tank overfill
and reduce the potential for escalation. Pages: 83
protection programs. For existing facilities, the results of a risk-based
4th Edition | May 2001 | Reaffirmed: March 2020
analysis of aboveground atmospheric petroleum storage tanks may indicate
Product Number: K20214 | Price: $145.00
the need for more protection against overfilling. In such cases, some
provisions from this standard may be suitable.
RP 2026
The purpose of this standard is to assist owner/operators and operating
Safe Access/Egress Involving Floating Roofs of Storage Tanks in
personnel in the prevention of tank overfills by implementation of a
Petroleum Service
comprehensive overfill prevention process (OPP). The goal is to receive
product into the intended storage tank without overfill or loss of containment.
Addresses the hazards associated with access/egress onto external and
internal floating roofs of in-service petroleum storage tanks and identifies
This standard does not apply to: underground storage tanks; aboveground
some of the most common practices and procedures for safely
tanks of 1320 U.S. gallons (5000 liters) or less; aboveground tanks which
accomplishing this activity. This RP is intended primarily for those persons
comply with PEI 600; pressure vessels; tanks containing non-petroleum
who are required to perform inspection, service, maintenance, or repair
liquids; tanks storing LPG and LNG; tanks at service stations; tanks filled
activities that involve descent onto floating roofs of in-service petroleum
exclusively from wheeled vehicles (i.e. tank trucks or railroad tank cars); and
tanks. Pages: 28
tanks covered by OSHA 29 CFR 1910.119 and EPA 40 CFR 68, or similar
regulations. Pages: 75
4th Edition | July 2022 | Product Number: K202604 | Price: $110.00
5th Edition | September 2020
Product Number: K235005 | Price: $135.00
RP 2207
Preparing Tank Bottoms for Hot Work
Addresses only the safety aspects of hot work performed on petroleum
storage tank bottoms. It discusses safety precautions for preventing fires,
explosions, and associated injuries. The term “hot work,” as used in this
publication, is defined as an operation that can produce a spark or flame
hot enough to ignite flammable vapors. RP 2009 provides more in-depth
information on safe hot work practices, and its requirements are not
duplicated here. Pages: 28
8th Edition | April 2022 | Product Number: K22078 | Price: $121.00
This publication is a new entry in this catalog.
This publication is related to an API licensing, certification, or accreditation program.
131
Health and Environmental Issues
NOTE Free publications with an asterisk are subject to a $10.00 handling charge for
also evaluated, and the results from the study were compared to those of an
each total order, plus actual shipping charges.
earlier study conducted in 1979. Adjustment factors to relate screening
values from one instrument are presented, which are applicable to
Air Research
marketing, transportation, and exploration and production facilities as well
as refineries. Pages: 128
EMISSIONS: GENERAL
August 1995 | Product Number: J33200 | Price: $98.00
API Guidance Document for GHG Reporting
Publ 342 and Publ 343
Drives consistency of voluntary reporting by individual oil and natural gas
Fugitive Emissions from Equipment Leaks I: Monitoring Manual and
companies of a core set of company-wide GHG indicators. This is intended
Fugitive Emissions from Equipment Leaks II: Calculation Procedures
to enhance comparability across company-by-company climate-related
for Petroleum Industry Facilities
reporting in the oil and natural gas industry, in order to provide decision
useful information to the financial sector, policy makers, industry customers,
A number of federal, state, and local regulations are designed to control
and other stakeholders. Pages: 40
fugitive emissions of volatile organic compounds and hazardous air
pollutants. API sponsored this project to present options and
1st Edition | March 2022 | You may download a PDF of this document
recommendations on procedures for obtaining inspection and maintenance
data from certain process equipment with the potential to leak fugitive
API-Template-for-Climate-related-Reporting-Initiative-March-2022.pdf
emissions. The two resulting manuals focus on the recommended fugitive
emission practices in the petroleum industry, specifically for refineries,
Compendium of Greenhouse Gas Emissions Estimation
marketing terminals, and the oil and gas production industries. Pages: 204
Methodologies for the Oil and Gas Industry
June 1998
API Tools for Estimating GHG Emissions
Product Number for Publ 342: J34200 | Price: $69.00
Product Number for Publ 343: J34300 | Price: $69.00
Accurate estimation of greenhouse gas emissions is indispensable to
responsibly addressing climate change. Through API, the U.S. oil and natural
gas industry has provided a suite of tools for estimating emissions. It
Publ 344
includes API's updated 2009 compendium of emissions estimation
Critical Review of Source Sampling and Analysis Methodologies
methodologies, software for emissions estimation and inventorying, and
for Characterizing Organic Aerosol and Fine Particulate Source
guidelines (created by the International Petroleum Industry Environmental
Emission Profiles
Conservation Association) to assist in the accounting and reporting of
emissions. Pages: 807
Intended for use in designing future measurement programs for
characterizing emissions from stationary sources that contribute to fine
August 2009 | Available for download at https://www.api.org/~/
particle concentrations in the atmosphere. The benefits and drawbacks of
media/files/ehs/climate-change/2009_ghg_compendium.ashx
various measurement approaches are discussed, and a recommended
approach for combustion sources is presented. Pages: 128
DR 141
June 1998 | Product Number: J34400 | Price: $80.00
Global Emissions of Carbon Dioxide from Petroleum Sources
Describes carbon dioxide emission estimates developed for a broadly
Publ 348
defined petroleum industry whose five segments include (1) exploration and
Air Toxics Emission Factors for Combustion Sources Using
extraction; (2) crude petroleum transportation to refineries; (3) refining
Petroleum-Based Fuels, Volume 1-Development of Emission
operations; (4) refinery products transportation; and (5) end uses. Emission
estimates for carbon dioxide have been developed for each industry
Factors Using API/WSPA Approach
segment and for each country. Activity factors describe the activity level for a
This project was performed with the cooperation of the California Air
particular industrial activity. Corresponding emission factors for each activity
Resources Board (CARB) and Western States Petroleum Association to
factor were developed from U.S. Environmental Protection Agency and
develop updated air toxic emission factors for combustion sources using
industry documents. Pages: 91
petroleum-based fuels. The emission factors developed using the best
July 1991 | Product Number: I00141 | Price: $65.00
available source testing information in this project will help the U.S.
Environmental Protection Agency to revise AP-42. In addition, the emission
Publ 326
factors will be integrated into CARB’s California Air Toxics Emission Factor
The Cost Effectiveness of VOC and NOx Emission Control Measures
database. Environmental, health, and safety engineers can use these
emission factors to develop more accurate and complete emission
Provides air pollution control planners and other interested parties in ozone
inventories without additional source testing, which could help facilities in
nonattainment areas with a “menu” of possible control options using the
the permitting process. Pages: 88
most up-to-date information and accurate analyses for significant sources of
August 1998 | Product Number: J34800 | Price: $109.00
volatile organic compounds (VOCs) and NOx. The menu provides a
preliminary demonstration of how cost-effective packages of attainment
Publ 4653
strategies and control measures can be developed to reduce VOC emissions
by 15 % by 1996. Appendices provide a detailed analysis of costs,
Fugitive Emission Factors for Crude Oil and Product Pipeline
effectiveness, and application limitations. Pages: 354
Facilities
September 1994 | Product Number: J32600 | Price: $160.00
Presents the results of a study to determine equipment component fugitive
emission factors for crude oil and product pipeline facilities. The emission
Publ 332
factors presented in this report will allow pipeline operators to estimate total
Comparison of Screening Values from Selected Hydrocarbon
hydrocarbon emissions from equipment components located at pipeline
Screening Instruments
facilities in light crude service, heavy crude service, and product service.
Pages: 50
Describes a study carried out at two refineries to compare differences in
June 1997 | Product Number: I46530 | Price: $86.00
equipment leak screening values obtained from four instruments commonly
used to measure fugitive emissions. The effect of screening distance was
This publication is a new entry in this catalog.
This publication is related to an API licensing, certification, or accreditation program.
133
Health and Environmental Issues
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Publ 4703
Consequently, it has been customary to refer to PM as being composed of
Gas Fired Boiler-Test Report Site A: Characterization of Fine
two PM components, filterable and condensable, the relative amounts of
each depending on the stack gas composition and temperature, control
Particulate Emission Factors and Speciation Profiles from Stationary
devices in use at the unit, and the method for measuring PM. While
Petroleum Industry Combustion Sources
measuring filterable PM is relatively straightforward (i.e. PM collected on a
In 1997, the U.S. Environmental Protection Agency (EPA) promulgated new
filter), condensable PM is a more esoteric quantity and its contribution to
ambient air standards for particulate matter (PM) smaller than
2.5
total PM emissions is very much dependent upon the choice of the
micrometers in diameter (PM 2.5). Source emissions data are needed to
measurement method. The U.S. Environmental Protection Agency apparently
assess the contribution of petroleum industry combustion sources to
recognized this issue, and until the interest in measuring and controlling
ambient PM 2.5 concentrations. This report presents particulate
PM 2.5 emissions emerged in the 1990s, their PM sampling methods were
measurement results from a 550,000 pounds per hour steam boiler firing
centered on measuring only filterable PM. At the time that these methods
refinery process gas. The particulate stack measurements were made using
were originally instituted, the best available pollution control devices were
both a dilution tunnel research test method and traditional EPA sampling
mainly limited to filterable PM and could not control the condensable
methods. Pages: 119
portion of PM emissions. As interest in the health effects associated with PM
emissions increased, efforts were centered on determining the contribution
July 2001 | Product Number: I47030 | Price: $96.00
of the PM 2.5 fraction that was believed to most responsible for these effects
and principally composed of condensable matter. This report will review the
Publ 4704
conditions leading to the formation of condensable particulate matter from
Gas Fired Heater-Test Report Site B: Characterization of Fine
stack gas components along with the methods used to measure PM
Particulate Emission Factors and Speciation Profiles from Stationary
emissions from refinery combustion sources. Pages: 27
Petroleum Industry Combustion Sources
September 2008 | Product Number: I47720 | Price: $68.00
In 1997, the U.S. Environmental Protection Agency (EPA) promulgated new
Publ 4775
ambient air standards for particulate matter (PM) smaller than
2.5 micrometers in diameter (PM 2.5). Source emissions data are needed
Simulating the Effect of Aerobic Biodegradation on Soil Vapor
to assess the contribution of petroleum industry combustion sources to
Intrusion into Buildings-Evaluation of Low Strength Sources
ambient PM 2.5 concentrations. This report presents particulate
Associated with Dissolved Gasoline Plumes
measurement results from a 114 million British thermal unit (MMBtu) per
hour gas-fired refinery process heater. The particulate stack measurements
Aerobic biodegradation can contribute significantly to the attenuation of
were made using both a dilution tunnel research test method and traditional
petroleum hydrocarbon vapors in the unsaturated zone; however, most
EPA sampling methods. Pages: 118
regulatory guidance for assessing potential human health risks via vapor
intrusion to indoor air either neglect biodegradation or only allow for one
August 2001 | Product Number: I47040 | Price: $96.00
order of magnitude additional attenuation for aerobically degradable
compounds, which may be overly conservative in many cases. This paper
Publ 4712
describes results from three-dimensional numerical model simulations of
Gas-Fired Steam Generator-Test Report Site C: Characterization of
vapor intrusion for petroleum hydrocarbons to assess the influence of
Fine Particulate Emission Factors and Speciation Profiles from
aerobic biodegradation on the attenuation factor for a variety of source
concentrations and depths for buildings with basements and slab-on-grade
Stationary Petroleum Industry Combustion Sources
construction. Provided that oxygen is present in the vadose zone, aerobic
In 1997, the U.S. Environmental Protection Agency promulgated new
biodegradation of petroleum hydrocarbon vapors in the unsaturated zone will
ambient air standards for particulate matter (PM) smaller than
reduce the soil gas concentrations and the potential risks from vapor
2.5 micrometers in diameter (PM 2.5). Source emissions data are needed
intrusion to indoor air compared to nondegrading compounds. At lower
to assess the contribution of petroleum industry combustion sources to
source concentrations and/or deeper source depths, aerobic biodegradation
ambient PM 2.5 concentrations. This report presents that the gas fired
may result in a reduction in vapor intrusion attenuation factors by many
steam generator has a maximum heat input of 62.5 MMBtu/Hr with an
orders of magnitude. The magnitude of the reduction depends on site-
average rate of approximately 50 MMBtu/hr. Pages: 100
specific conditions, which should be considered in the development of a
July 2001 | Product Number: I47120 | Price: $90.00
conceptual site model for each site. However, oxygen supply and
degradation rates are likely to be sufficient at many sites to mitigate potential
risks from vapor intrusion for low vapor concentration sources (less than
Publ 4720
about 2 mg/L-vapor total hydrocarbons). The simulations conducted in this
Comparison of API and EPA Toxic Air Pollutant Emission Factors for
study provide a framework for understanding the degree to which bio-
Combustion Sources
attenuation will occur under a variety of scenarios and provide insight into
site conditions that will result in significant biodegradation. This improved
Compares and explains differences in published toxic air pollutant emission
understanding may be used to select site-specific attenuation factors for
factors for combustion sources and recommends priorities for gathering
degradable compounds and develop soil vapor screening levels appropriate
additional emission factor information. Pages: 50
for particular combinations of source concentrations, source depth, and
September 2002 | Product Number: I47200 | Price: $100.00
building characteristics, which should be defined as part of a site conceptual
model. Pages: 53
Publ 4772
April 2009 | Product Number: I47750 | Price: $117.00
Measuring Particulate Emissions from Combustion Sources
Since the inception of the Clean Air Act, the petroleum refining industry has
Publ 4776
been faced with the need to determine criteria pollutant emissions from
A Guide to Understanding, Assessment and the Regulation of PAHs
combustion sources. While some of these species, such as NOx, SO2, and
in the Aquatic Environment
CO remain in the vapor phase during and after combustion and are relatively
simple to measure, particulate matter (PM) measurements are much more
Designed to be an introductory guide to understanding and assessing
challenging. This is because while some PM such as fly ash or catalytic
polycyclic aromatic hydrocarbons (PAHs) in the aquatic environment
cracking catalyst fines is clearly solid material that is readily collected and
(water and sediments). API prepared this guide primarily for refinery
measured on a sampling filter, other species that may exist in the vapor
personnel and home office environmental staff who may have to address
phase during combustion can later condense into aerosols downstream from
PAH issues. In addition, this guide may also be useful to staff in regulatory
the combustion zone. This can occur before or after any control devices,
depending upon the temperature and composition of the combustion gases.
134
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agencies that work with PAHs in wastewater discharge permits, waste load
Publ 4662
allocations (total maximum daily loadings), and sediment investigation
Evaluation of a Petroleum Production Tank Emissions Model
and remediation.
E&P TANK was evaluated for petroleum production tanks in an emission
The guide provides an overview on the chemistry, fate, and sources of PAHs
measurement project sponsored by API and the Gas Research Institute.
in the environment and the regulatory implications. The guide also includes
Emission testing was performed on storage tank vents located at seven sites
descriptions of the different sources of PAHs (petrogenic, pyrogenic,
in widely diverse oil and gas producing regions across the United States.
diagenic, biogenic) and techniques for differentiating these sources through
Measured emissions were found to be in agreement with E&P TANK model
their characteristic fingerprints, including straightforward ways to help identify
predictions. Pages: 338
or rule out potential sources. Pages: 60
October 1997 | Product Number: I46620 | Price: $128.00
September 2011 | Product Number: I47760 | Price: $116.00
Publ 4679
EMISSIONS: EXPLORATION AND PRODUCTION
Amine Unit Air Emissions Model and User’s Guide, AMINECalc
Publ 4589
Version 1.0
Fugitive Hydrocarbon Emissions from Oil and Gas Production
AMINECalc is a user-friendly Windows®-based software program that
Operations
estimates hydrocarbon emissions from amine-based sour gas and natural
The emission factors derived in this report indicate that fugitive emissions
gas liquid sweetening units. The output generated by the software can be
from production facilities are considerably lower than they were in the late
used for regulatory reporting by unit operators according to the requirements
1970s. Investigators use portable detectors to screen more than 180,000
of the Clean Air Act Amendments of 1990. AMINECalc performs three types
components at 20 offshore and onshore facilities. Mass emission rates from
of calculation options: (1) mass balance calculation, (2) gas process (gas
“bagged” emitters, valves, connectors, and other components, such as seals
feed) simulation, and (3) NGL process (liquid feed) simulation. Mass
and vents, are used to develop emission factors for individual components
emission rates of hazardous air pollutants, including benzene, toluene,
and groups of components. A workbook included in the report provides site
ethylbenzene, and xylenes (BTEX), and volatile organic compounds can be
operators with three different options to calculate emissions from their
estimated with the use of AMINECalc. System requirements for running
facilities. See also Publ 4615. Pages: 263
AMINECalc Version 1.0 are IBM PC 486 compatible or higher, 8 MB RAM or
more, and Windows® 95/98/NT. Approximately 2 MB of hard disk space are
December 1993 | Product Number: I45890 | Price: $154.00
required to hold the program and its supporting run-time libraries. For better
interface viewing, it is recommended that the user set the monitor to a high
Publ 4615
color 16 bit (or higher) resolution. See also Publ 4680. Pages: 76
Emission Factors for Oil and Gas Production Operation
January 1999 | Product Number: I46790 | Price: $535.00
Supplements the information found in Publ 4589 and contains revised
emission factors developed from 1993 API data using correlation equations
Publ 4680
established by the U.S. Environmental Protection Agency in 1994. The report
contains emissions factors for five types of production operations-light
Amine Unit Air Emissions Model Evaluation
crude production, heavy crude production, gas production, gas processing
The implementation of the 1990 Clean Air Act Amendments in the United
plants, and offshore production. It also contains profiles of speciated
States has created the need for a reliable method to estimate and report
emissions including air toxics and assesses regional differences in fugitive
hydrocarbon emissions from amine units. A simulation package, called
emissions and control efficiency of inspection and maintenance programs.
Amine Unit Air Emission Model (AMINECalc) Version 1.0 was developed. This
Component inventory data, screening data, and leak emission data are also
report evaluates the AMINECalc model by comparing the simulation results
included. See also Publ 4589. Pages: 56
with field data collected from operating gas plants. It also recommends
January 1995 | Product Number: I46150 | Price: $67.00
improvements and modifications to refine the predictions. See also
Publ 4679. Pages: 96
Publ 4638
December 1998 | Product Number: I46800 | Price: $131.00
Calculation Workbook for Oil and Gas Production Equipment
Fugitive Emissions
Publ 4683
This workbook, which is the result of five years of field testing of equipment
Correlation Equations to Predict Reid Vapor Pressure and Properties
components at production facilities across the United States, is a valuable
of Gaseous Emissions for Exploration and Production Facilities
tool for petroleum producers who are interested in estimating fugitive
emissions from their oil and gas production sites. Four methods of
Establishes simple techniques for exploration and production (E&P)
calculating fugitive emissions are presented: EPA average emission factor
operators of petroleum storage tank facilities to use for the preparation of
method, EPA screening value range emission method, EPA correlation
site-specific emission inventories to meet environmental regulations.
method, and leak quantification method. Pages: 62
Analyses were performed of oil and gas sampling results and emissions
July 1996 | Product Number: I46380 | Price: $67.00
modeling results for more than 100 crude oil E&P storage tanks. Correlation
equations or statistical averages were recommended to estimate Reid Vapor
Pressure, vented flash gas molecular weight, vented working and standing
Publ 4661
gas molecular weight, hydrocarbon speciation (including hazardous air
Exploration and Production Emission Calculator II (EPEC II) User's
pollutants), and separator gas specific gravity. Pages: 82
Guide
December 1998 | Product Number: I46830 | Price: $86.00
The Exploration and Production Emission Calculator Version 2.0 (EPEC II) is
a software tool that can be used to estimate emissions for exploration and
Publ 4697
production facilities. EPEC II integrates user inputs, emission calculations,
and data summaries for many equipment types common to exploration and
Production Tank Emissions Model (E&P TANK, Version 3.0)
production facilities. The calculation techniques and emission factors utilized
E&P TANKS (API Publ 4697) is a computer-based software designed to use
by the EPEC II software were, in most cases, established by the U.S.
site-specific information to predict emission from petroleum production
Environmental Protection Agency, API, and the Gas Research Institute.
storage tanks, now compatible with 32-bit and 64-bit Windows 7 as well as
Published references that provide background information for the calculation
Windows 2000/XP/Vista. It estimates flashing, working, and standing losses
methods used in EPEC II are given for each equipment type in both the
and calculates losses using specific operations for each user's tank. Cited by
software and in each section of this user's guide. Pages: 96
the Environmental Protection Agency (EPA), it allows the user to enter
2nd Edition | January 2007 | Product Number: I46610 | Price: $136.00
specific tank condition information to generate air emission reports.
This publication is a new entry in this catalog.
This publication is related to an API licensing, certification, or accreditation program.
135
Health and Environmental Issues
To purchase individual API standards, visit apiwebstore.org
API has discontinued the sale of E&P Tanks v3.0; no new licenses for the
Publ 4678
software will be issued.
Fugitive Emissions from Refinery Process Drains, Volume II,
Existing customers should contact support@eptanks.com for assistance in
Fundamentals of Fugitive Emissions from Refinery Process Drains
transferring an existing E&P Tanks v3.0 license from one user to another user.
Volume two of a three-part study initiated by API to update the AP-42 emission
API will continue to offer support for existing customers who encounter errors
factor for refinery process drains, which may overestimate refinery process
inputting data into software in accordance with E&P Tanks user guide
drain fugitive emissions. This volume describes theoretical concepts and
(Publication 4697).
equations that may be used in a model (APIDRAIN) to estimate speciated
(Note that API provides no support for earlier versions of E&P Tanks.)
volatile organic compound emissions. The model can provide insight on how to
change process drain variables (flow rate, temperature, etc.) to reduce
EMISSIONS: MARKETING
emissions. See also Publ 4639, Publ 4677, and Publ 4681. Pages: 104
April 1999 | Product Number: I46780 | Price: $105.00
Publ 4588
Development of Fugitive Emission Factors and Emission Profiles for
Publ 4681
Petroleum Marketing Terminals, Volume 1
Fugitive Emissions from Refinery Process Drains, Volume III, Process
Drain Emission Calculator: APIDRAIN Version 1.0
To evaluate the accuracy of fugitive emission estimates for petroleum
marketing terminals, a study was designed to determine average emission
Volume three of a three-part study-the computer model with user’s guide to
factors and fugitive emission correlation equations for components in light
estimate emissions from refinery process drains. APIDRAIN is a user-friendly
liquid and gas vapor services. Four marketing terminals were tested, and the
Windows®-based software program operating under the Microsoft Excel® for
results of the study are presented in this report. See also appendices to this
Windows® environment. The model allows the user to sum up the emissions
document, Publ 45881. Pages: 146
from a refinery process unit area or from the entire refinery. The model user
can quickly and easily predict the contribution of process drain emissions to
May 1993 | Product Number: I45880 | Price: $134.00
the total emission inventory of a refinery. Unit operators can use the output
generated by the software for regulatory reporting according to the
Publ 45881
requirements of the Clean Air Act Amendments of 1990. The minimum
Development of Fugitive Emission Factors and Emission Profiles for
system requirements for running APIDRAIN Version 1.0 are PC 486 DX2
Petroleum Marketing Terminals, Volume 2
Windows® 3.11 platform, 8 MB RAM, and Windows 95®/Windows NT®. The
user must have Windows® and Excel® installed on a personal computer to
This volume is the appendix to Publ 4588. Appendices include statistical
begin using the software. The APIDRAIN model is enhanced with automatic
analyses of data, field inventory sheet data, emitter data, nonaromatic
functions that enable the user to easily summarize important reporting
speciation data, and aromatic speciation data. See also Publ 4588.
information and to generate tabular emissions totals for both specific
Pages: 217
refinery process units and for the entire refinery. It is not necessary for the
May 1993 | Product Number: I45881 | Price: $124.00
user to possess a rigorous understanding of Excel® to use APIDRAIN; only a
few common principles of the Windows® operating environment are needed
(such as point-and-click and navigation of tab and arrow keys). See also
EMISSIONS: REFINING
Publ 4639, Publ 4677, and Publ 4678. Pages: 92
April 1999 | Product Number: I46810 | Price: $446.00
Validation of Heavy Gas Dispersion Models with Experimental
Results of the Thorney Island Trials
Publ 4713
Volumes I & II
Test Report: Fluidized Catalytic Cracking Unit at a Refinery (Site A),
June 1986
Characterization of Fine Particulate Emission Factors and Speciation
Profiles from Stationary Petroleum Industry Combustion Sources
Publ 4587
There are few existing data on emissions and characteristics of fine aerosols
Remote Sensing Feasibility Study of Refinery Fenceline Emissions
from petroleum industry combustion sources, and the limited information that
Reviews the state of the art of optical remote sensing (ORS) technology and
is available is incomplete and outdated. API developed a test protocol to
examines the potential use of ORS systems combined with ancillary
address this data gap, specifically to:
measurements, such as meteorological and tracer gas release data to
develop emission factors and speciation profiles for emissions of primary
determine fugitive emission rates. The report also highlights some issues to
fine particulate matter (i.e. particulate present in the stack flue gas
consider in planning an ORS field study and clarifies the attendant tradeoffs
including condensable aerosols), especially organic aerosols from gas-
for issues such as selection of appropriate ORS systems, consideration of
fired combustion devices, and
detection limits and beam placement, choice of dispersion models, use of
identify and characterize secondary particulate (i.e. particulate formed via
tracer gas releases, time scale and timing of field studies, and the requisite
reaction of stack emissions in the atmosphere) precursor emissions.
meteorological measurements. Pages: 105
This report presents the results of a pilot project to evaluate the test protocol
April 1994 | Product Number: I45870 | Price: $76.00
on a refinery fluid catalytic cracking unit. Pages 113
March 2002 | Product Number: I47130 | Price: $157.00
Publ 4677
Fugitive Emissions from Refinery Process Drains, Volume I, Fugitive
Publ 4723-A
Emission Factors for Refinery Process Drains
Refinery Stream Composition Data-Update to Speciation Data in
Emissions from refinery process drains are under increasing scrutiny,
API 4723
particularly with regard to volatile organic compounds (VOCs) and hazardous
Since the publication of API 4723 in 2002, new regulatory requirements
air pollutants because of the Clean Air Act Amendments of 1990. This
have resulted in many changes in refinery processes that may have altered
publication is volume one of a three-part study initiated by API to update the
process stream compositions. Changing feedstocks, new process additives,
AP-42 emission factor for refinery process drains, which may overestimate
and new catalysts may also have affected the concentrations of chemical
refinery process drain fugitive emissions. This volume contains simplified
species present in specific process streams.
emission factors that can be used to quickly estimate total VOC emissions
from refinery process drains. See also Publ 4639, Publ 4678, and
Based on an assessment of the range and depth of more recent stream
Publ 4681. Pages: 132
speciation data, the Petroleum Environmental Research Forum (PERF)
elected to update the stream speciation profiles in API 4723 using more
April 1999 | Product Number: I46770 | Price: $105.00
136
This publication is a new entry in this catalog.
This publication is related to an API licensing, certification, or accreditation program.
Health and Environmental Issues
To purchase individual API standards, visit apiwebstore.org
recent composition sampling. The updated profiles are provided in this
Publ 4622
report. PERF members believe that the newer data are more representative
Petroleum Industry Data Characterizing Occupational Exposures to
due to improved sampling and analytical techniques and that these newer
Methyl Tertiary Butyl Ether (MTBE): 1983-1993
analyses better reflect changes in refinery operations over recent years.
A large database of records was collated for the current study, representing
Describes the results of a survey of API member companies to acquire data
information from 25 refineries.
relating to occupational exposure to MTBE for various activities associated
with petroleum facilities. It provides a detailed description of the survey
The original study reported on 24 chemical species and the current study
questionnaire as well as a statistical analysis of some 1,833 workplace
provides data on 89 species. The original study reported on 65 refinery
concentration measurements associated with potential occupational
process streams and the current project provides data on 68 process
exposures. Pages: 105
streams.
August 1995 | Product Number: I46220 | Price: $67.00
The material contained in this report will be of use in estimating the
emissions of specific chemical species, preparing permit applications, and
Publ 4625
performing other environmental assessments. API, PERF, and the project
participants make no claims as to the suitability or acceptability of the
Service Station Personnel Exposures to Oxygenated Fuel
stream composition data reported herein for specific reporting or regulatory
Components
purposes. Pages: 278
Describes a study in four ozone nonattainment areas to measured
December 2018 | Product Number: I4723A | Price: $158.00
exposures of refueling attendants and mechanics to fuel oxygenate
species-methyl ttertiary butyl ether, tertiary amyl methyl ether, tertiary
EMISSIONS: VEHICLES
butyl alcohol, ethanol, and butyl alcohol-at service stations. The
aromatics-benzene, toluene, xylene, para-xylene, and ethylbenzene-
Publ 4642
were also measured. Full shift (approximately 8-hour time-weighted
average) and short-term (15-20 minutes) samples were collected at
A Study to Quantify On-Road Emissions of Dioxins and Furans from
each station. Volatility and meteorological measurements were also
Mobile Sources: Phase 2
taken. Pages: 144
Presents the results of a study to assess on-road emissions of dioxins and
August 1995 | Product Number: I46250 | Price: $71.00
furans from light- and heavy-duty vehicles in the United States. This study
was conducted in response to the U.S. Environmental Protection Agency’s
Publ 4629
(EPA) draft dioxin reassessment document, which was based on data
Hexavalent Chromium Exposures During Hot Work
developed from studies conducted outside of the United States. Emissions
were measured in the Fort McHenry Tunnel in Baltimore, MD, based on
Details the findings from an air sampling survey contracted by API to evaluate
techniques tested and proven in Phase 1 of this study. The emission factor
inhalation exposures to hexavalent chromium [chromium (VI)] during seven
determined for heavy-duty diesel vehicles in this work was less than the EPA
types of hot work: carbon arc cutting (CAC), flux cored arc welding (FCAW), gas
estimate. Pages: 96
metal arc welding (GMAW or MIG), grinding, gas tungsten arc welding (GTAW or
December 1996 | Product Number: I46420 | Price: $141.00
TIG), oxyfuel gas cutting (OFC or torch cutting), and shielded metal arc welding
(SMAW or stick). After the First Edition of this report was published, it was
determined that 15 samples from one of the projects were listed as carbon
Publ 4646
steel base metal and should have been listed as stainless steel. While the
Evaluation of Fuel Tank Flammability of Low RVP Gasolines
original report was careful to point out the use of electrodes typical for stainless
Twenty-two test fuels were varied with respect to Reid vapor pressure (RVP),
work, it was felt that a complete update was needed. Eighty-three samples
pentane-to-butane ratio, and addition of ethanol and methyl tert-butyl ether
were collected in October and November 2005 at two petroleum sites during
(MTBE), to evaluate the conditions under which vapors from reformulated
maintenance turnarounds by API member companies. An additional 188
gasoline contained in automobile fuel tanks become flammable. The results
samples were collected April-June 2006 at three different petroleum company
show that temperature limits of flammability correlate with RVP; the addition
sites by ICU Environmental Health and Safety. Of the 271 total samples, 63
of ethanol or MTBE or both affects the upper flammability limits; and the
samples were at or above the Occupational Safety and Health Administration
ratio of pentane to butane has no consistent effect at similar RVP levels.
(OSHA) action level of 2.5 μg/m3 and 51 were at or above the OSHA
Pages: 144
permissible exposure limit of 5 μg/m3. Pages: 12
December 1996 | Product Number: I46460 | Price: $105.00
June 2007 | Product Number: I46290 | Price: $93.00
EXPOSURE: ASSESSMENT AND MONITORING
MODELING
Publ 4617
Publ 4546
A Monte Carlo Approach to Generating Equivalent Ventilation Rates
Hazard Response Modeling Uncertainty (a Quantitative Method):
in Population Exposure Assessments
Evaluation of Commonly-Used Hazardous Gas Dispersion Models-
Volume 2
Describes a study to improve breathing rate simulations in computer-based
models used to estimate the exposures of urban populations to ozone and
Contains an evaluation of a group of 14 hazardous gas dispersion models.
carbon monoxide. Algorithms producing equivalent ventilation rate values
All available measurement programs were considered for the evaluation,
according to age, gender, activity, activity duration, and breathing rate
covering both the releases of dense gases and nondense tracer gases; eight
category were developed from measured rates in primary-school children,
data sets are used in the evaluation. The models are reviewed for their
high-school children, outdoor adult workers, and construction workers. Seven
scientific validity. Statistical procedures and residual plots are used to
additional time/activity databases not used in the current pNEM
characterize performance. A number of the models give predictions that
methodology are described as well as models simulating maximum
reasonably match field data. Pages: 351
sustainable ventilation rates as a function of exercise duration, age, and
October 1992 | Product Number: I45460 | Price: $154.00
gender. Pages: 168
March 1995 | Product Number: I46170 | Price: $86.00
This publication is a new entry in this catalog.
This publication is related to an API licensing, certification, or accreditation program.
137
Health and Environmental Issues
To purchase individual API standards, visit apiwebstore.org
Publ 4628
Environment and Safety Data
A Guidance Manual for Modeling Hypothetical Accidental Releases
The following summaries report on cases that are recorded under the U.S.
to the Atmosphere
Bureau of Labor Statistics’ recordkeeping guidelines. The surveys are based
Presents methods for modeling hypothetical accidental releases of fluids
on data submitted to API by oil and gas companies. The reports include
and gases into the atmosphere from process operations. Given a particular
information regarding injuries, illness, fatalities, lost workday cases, and
type of release and the chemicals or petroleum fractions involved, methods
incidence rates by function.
for modeling the release and subsequent dispersion phenomena are treated
in a step-wise, comprehensive manner. Detailed simulation of eight
1989 Summary of Occupational Injuries, Illnesses, and Fatalities in
hypothetical release scenarios are presented to demonstrate how the
the Petroleum Industry
modeling procedures can be implemented. Pages: 212
January 1989 | Product Number: K19996 | Price: $64.00
November 1996 | Product Number: I46280 | Price: $154.00
1990 Summary of Occupational Injuries, Illnesses, and Fatalities in
Publ 4669
the Petroleum Industry
Review of Air Quality Models for Particulate Matter
July 1991 | Product Number: K19988 | Price: $89.00
API has published a review of existing source and receptor models
available for analyzing particulate matter (PM) concentrations. This report
1991 Summary of Occupational Injuries, Illnesses, and Fatalities in
critically reviews existing air modeling tools for PM, recommends models
the Petroleum Industry
for State Implementation Plan applications, and identifies areas where the
models need improvement. If you would like API to provide you with a hard
September 1992 | Product Number: K19987 | Price: $89.00
copy of this publication for a cost of $45.00, please contact the
Intellectual Property Department at API, 1200 Massachusetts Avenue NW,
1992 Summary of Occupational Injuries, Illnesses, and Fatalities in
Suite 1100, Washington, DC 20001-5571; e-mail: apipubs@api.org;
the Petroleum Industry
phone: 202-682-8156. Pages: 311
August 1993 | Product Number: K19986 | Price: $89.00
March 1998
1993 Summary of Occupational Injuries, Illnesses, and Fatalities in
OZONE
the Petroleum Industry
Publ 305
June 1994 | Product Number: K19985 | Price: $104.00
Protecting Agricultural Crops from Ozone Exposures-Key Issues and
1994 Summary of U.S. Occupational Injuries, Illnesses, and
Future Research Directions
Fatalities in the Petroleum Industry
Identifies and reviews some of the key issues related to assessing the effects
of ozone exposure on vegetation. This report analyzes information on
June 1995 | Product Number: K19984 | Price: $104.00
components of ozone exposure that elicit adverse effects on vegetation; ways
to describe these components in the form of ozone exposure indices that
1995 Summary of U.S. Occupational Injuries, Illnesses, and
may be useful in the standard-setting process for protecting vegetation; the
Fatalities in the Petroleum Industry
change in nonattainment status that may occur should the existing ozone
national ambient air quality standards be modified; and the need for future
May 1996 | Product Number: K19983 | Price: $104.00
research efforts to explore the development of a suitable multiparameter
index to protect vegetation from ozone exposure. Pages: 156
Publ 2375
August 1991 | Product Number: J30500 | Price: $90.00
1996 Summary of Occupational Injuries, Illnesses, and Fatalities in
the Petroleum Industry
Publ 309
June 1997 | Product Number: K23751 | Price: $104.00
Current Status and Research Needs Related to Biogenic
Hydrocarbons
Publ 2376
Describes the literature on the state of science on biogenic hydrocarbons.
1997 Summary of Occupational Injuries, Illnesses, and Fatalities in
Among the areas covered are biogenic emission measurements, ambient
the Petroleum Industry
concentration measurements, emission inventories, chemical kinetics, and
modeling studies from 1960 to 1992. The results of the review are used to
June 1998 | Product Number: K23761 | Price: $104.00
identify areas of understanding as well as uncertainty in present-day
knowledge. A list of references with 163 abstracts is included. Pages: 240
Publ 2377
June 1992 | Product Number: J30900 | Price: $122.00
1998 Summary of Occupational Injuries, Illnesses, and Fatalities in
the Petroleum Industry
Publ 4616
March 1999 | Product Number: K23771 | Price: $112.00
The Importance of Using Alternative Base Cases in Photochemical
Modeling
Publ 2378
A series of Urban Airshed Model sensitivity studies were conducted using two
1999 Survey on Petroleum Industry Occupational Injuries, Illnesses,
summer O3 episodes. Plausible alternative conditions were established to
and Fatalities Summary Report: Aggregate Data Only
define acceptable base cases, some of which provided model performance
June 2000 | Product Number: K23781 | Price: $112.00
comparable to the best achieved for the episodes. The alternative base
cases used in this study produced significant differences in estimates of the
air quality benefits of hypothetical emissions reductions. The study strongly
Publ 2379
recommends that current photochemical modeling practices include this
2000 Survey on Petroleum Industry Occupational Injuries, Illnesses,
type of analysis to reduce the risk of focusing on the wrong ozone precursor,
and Fatalities Summary Report: Aggregate Data Only
underestimating control requirements, or incurring costs to implement
unnecessary controls. Pages: 364
March 2001 | Product Number: K23790 | Price: $112.00
September 1994 | Product Number: I46160 | Price: $149.00
138
This publication is a new entry in this catalog.
This publication is related to an API licensing, certification, or accreditation program.
Health and Environmental Issues
To purchase individual API standards, visit apiwebstore.org
Publ 2380
Human Health Related Research
2001 Survey on Petroleum Industry Occupational Injuries, Illnesses,
TR 400
and Fatalities Summary Report: Aggregate Data Only
Toluene: A Preliminary Study of the Effect of Toluene on Pregnancy of
March 2002 | Product Number: K23801 | Price: $112.00
the Rat
Publ 2381
Describes a preliminary experiment performed on the pregnant rat to
2002 Survey on Petroleum Industry Occupational Injuries, Illnesses,
determine appropriate exposure levels of toluene, for future investigation of
embryofetal toxicity in the rat when administered via the inhalation route
and Fatalities Summary Report: Aggregate Data Only
from days 5 to 15 of pregnancy inclusive. The inhalation route of
June 2003 | Product Number: K23811 | Price: $112.00
administration was chosen as the most likely route of exposure in humans.
The exposure levels were chosen following a review of currently available
Publ 2382
information. See related document TR 401. Pages: 113
2003 Survey on Petroleum Industry Occupational Injuries, Illnesses,
June 1993 | Product Number: I00400 | Price: $67.00
and Fatalities Summary Report: Aggregate Data Only
May 2005 | Product Number: K23821 | Price: $112.00
TR 401
Toluene: The Effect on Pregnancy of the Rat
Publ 2383
Describes a study to assess the toxicity of toluene on the pregnant rat as well
2004 Survey on Petroleum Industry Occupational Injuries, Illnesses,
as on the developing fetus. Pregnant rats were exposed to 250, 750, 1500,
and Fatalities Summary Report: Aggregate Data Only
and 3000 ppm toluene via inhalation for 6 hours a day from days 6 to 15 of
March 2005 | Product Number: K23831 | Price: $112.00
pregnancy. Control rats were exposed to filtered air for the same length of
time. Throughout the exposure period, animals were observed for clinical
Publ 2384
signs of toxicity. On day 20, the females were sacrificed and examined for
abnormalities. The number and distribution of live young as well as the
2005 Survey on Petroleum Industry Occupational Injuries, Illnesses,
number of fetal deaths and abnormalities were also recorded. See related
and Fatalities Summary Report: Aggregate Data Only
document TR 400. Pages: 215
May 2006 | Product Number: K23841 | Price: $112.00
June 1993 | Product Number: I00401 | Price: $95.00
Publ 2385
TR 403
2006 Survey on Petroleum Industry Occupational Injuries, Illnesses,
Closed-Patch Repeated Insult Dermal Sensitization Study of TAME
and Fatalities Summary Report: Aggregate Data Only
in Guinea Pigs
June 2007 | Product Number: K23851 | Price: $112.00
Describes a study to evaluate the allergic contact sensitization potential of
tert-amyl methyl ether (TAME) in guinea pigs. Observations for mortality were
Publ 2386
made daily. Body weights were obtained and general health monitored
2007 Survey on Petroleum Industry Occupational Injuries, Illnesses,
weekly. Dermal evaluations were made approximately 24 and 48 hours after
and Fatalities Summary Report: Aggregate Data Only
exposure. Pages: 32
February 1995 | Product Number: I00403 | Price: $67.00
May 2008 | Product Number: K23861 | Price: $112.00
TR 404
Publ 2387
An Inhalation Oncogenicity Study of Commercial Hexane in Rats and
2008 Survey on Petroleum Industry Occupational Injuries, Illnesses,
Mice, Part I-Rats
and Fatalities Summary Report: Aggregate Data Only
This abridged report, the first part of a two-part set, evaluates the oncogenic
March 2009 | Product Number: K23871 | Price: $112.00
potential of commercial hexane administered to four groups of 50 Fischer
344 rats at concentrations of 0, 900, 3000 and 9000 ppm in air. Summary
Publ 2388
text as well as pertinent data on changes in body weight, pathology, and
2009 Survey on Petroleum Industry Occupational Injuries, Illnesses,
individual and overall tumor incidence including differences in survivorship
and Fatalities Summary Report: Aggregate Data Only
between control and exposed groups are provided. The amendment and
table of contents to the unabridged final report are included. Pages: 152
April 2010 | Product Number: K23881 | Price: $112.00
January 1995 | Product Number: I00404 | Price: $86.00
Publ 4714
TR 405
A Guide to Polycyclic Aromatic Hydrocarbons for the Non-Specialist
An Inhalation Oncogenicity Study of Commercial Hexane in Rats and
Provides an introduction to polycyclic aromatic hydrocarbons (PAHs) for
Mice, Part II-Mice
persons working in the petroleum industry. It describes in general terms what
This abridged report, the second part of a two-part set, evaluates the
PAHs are and how they are formed; PAH environmental transport, fate, and
oncogenic potential of commercial hexane administered to four groups of 50
health effects; regulatory requirements related to PAHs; and analytical
B6C3F1 mice at concentrations of 0, 900, 3000 and 9000 ppm in air.
methods for measuring PAH concentrations in the environment. This
Summary text and pertinent data on differences in survivorship between
information is of particular relevance to the petroleum industry due to the
control and exposed groups, changes in body weight, and pathology are
natural presence of PAHs in crude oil, the formation of PAHs during some
provided. The table of contents to the unabridged final report is included.
refining processes, and the potential for production of PAHs during the
Pages: 106
combustion of petroleum products. The intended audience for this report
includes environmental professionals who must address PAH regulatory
January 1995 | Product Number: I00405 | Price: $67.00
issues and field personnel who are responsible for the sampling and
analyses of PAHs. Pages: 36
February 2002 | Product Number: I47141 | Price: $86.00
This publication is a new entry in this catalog.
This publication is related to an API licensing, certification, or accreditation program.
139
Health and Environmental Issues
To purchase individual API standards, visit apiwebstore.org
TR 409
Publ 4623
Primary Skin Irritation Study in Rabbits of API 91-01 and PS-6
Anecdotal Health-Related Complaint Data Pertaining to Possible
Unleaded Test Gasolines
Exposures to Methyl Tertiary Butyl Ether (MTBE): 1993 and 1994
Follow-Up Surveys
Describes a study conducted to assess primary dermal irritation data for two
motor fuels according to Toxic Substances Control Act and Federal
Describes the development and administration of an informal survey of API
Hazardous Substances Act guidelines. Test rabbits were exposed dermally to
member companies and state agencies to acquire anecdotal complaint data
unleaded gasoline according to a specified protocol and observed daily for
relating to MTBE exposure. Data associated with 71 occupational and 13
signs of skin irritation. Such information is valuable for accurate hazard
nonoccupational health-related complaints including reported symptoms are
assessment and first aid treatment. Pages: 58
presented. Pages: 33
March 1995 | Product Number: I00409 | Price: $67.00
September 1995 | Product Number: I46230 | Price: $67.00
TR 410
Publ 4634
Chromosome Aberrations in Chinese Hamster Ovary (CHO) Cells
Index and Abstracts of API Health-Related Research
Exposed to Tertiary Amyl Methyl Ether (TAME)
This compendium of health-related research provides author, organization,
and subject indices for research investigations and scientific reviews
Evaluates the clastogenic potential of TAME using CHO cells compared to the
conducted for API between 1959 and 1994. It covers industrial hygiene and
solvent control group. Based on the findings of this study, TAME was
exposure assessment, toxicology, environmental biology, product safety, and
concluded to be positive for the induction of structural chromosome
community and occupational health research areas. Informative abstracts
abberations in CHO cells. Pages: 56
provide useful background on each study and give information on
December 1996 | Product Number: I00410 | Price: $95.00
publication availability. Pages: 160
September 1995 | Product Number: I46340 | Price: $86.00
TR 411
Chinese Hamster Ovary (CHO) HGPRT Mutation Assay of Tertiary
Publ 4647
Amyl Methyl Ether (TAME)
Brain Glial Fibrillary Acidic Protein (GFAP) as a Marker of
Describes a study conducted to evaluate the mutagenic potential of the test
Neurotoxicity During Inhalation Exposure to Toluene
article, TAME based on quantitation of forward mutations at the
Evaluates the concentration of GFAP in the rat’s brain as a practical
hypoxanthine-guanine phosphoribosyl transferase (HGPRT) locus of CHO
biomarker of toluene-induced neurotoxicity. Adult male rats received
cells. Under the conditions of this study, TAME was concluded to be negative
inhalation exposure to toluene scfromheduled to approximate occupational
in the CHO/HGPRT mutation assay. Pages: 46
exposure for up to 42 days. During and after exposure, the concentration of
December 1996 | Product Number: I00411 | Price: $95.00
GFAP was determined in four brain regions and compared with standard
criteria of neurotoxicity: behavioral or neuropathological changes. Pages: 44
TR 412 and TR 414
June 1997 | Product Number: I46470 | Price: $86.00
A Range-Finding Developmental Inhalation Toxicity Study of
Unleaded Gasoline Vapor Condensate in Rats and Mice via Whole-
Publ 4648
Body Exposure and an Inhalation Developmental Toxicity Study of
Human Neurobehavioral Study Methods: Effects of Subject Variables
Unleaded Gasoline Vapor Condensate in the Rat via Whole-Body
on Results
Exposure
Behavioral tests from two consensus neurotoxicity batteries were
This two-part inhalation study sought to specifically evaluate the potential of
administered to 715 subjects aged 26-45. These people had 0-18 years of
unleaded gasoline for developmental toxicity in rodents. The composition of
education and represented the following cultural groups: European-descent
the unleaded gasoline vapor condensate and the treatment pattern used are
majority, Native American Indian, African American, and Latin American.
representative of real-world exposure conditions encountered at service
Differences in educational level and locale (rural vs. urban) and gender were
stations and in other occupational settings. The results show that
examined. All factors affected the outcome of the behavioral tests studied.
developmentally there were no differences between treated and control
Results suggested that education and cultural group should be controlled in
groups in malformations, total variations, resorptions, fetal body weight, or
the design of the study rather than in the statistical analysis, and failure to
viability. Under the conditions of the study, unleaded gasoline vapors did not
do so could lead to false conclusions about the presence or absence of
produce evidence of developmental toxicity. (This volume includes
neurotoxic effects. Pages: 110
publications TR 412 and TR 414.) Pages: 300
December 1996 | Product Number: I46480 | Price: $105.00
April 1998 | Product Number: I00412 | Price: $105.00
Publ 4689
Publ 4592
Chemical Human Health Hazards Associated with Oil Spill Response
Odor Threshold Studies Performed with Gasoline and Gasoline
Combined with MTBE, ETBE and TAME
Contains an overview of human health hazards that could be encountered by
personnel involved with spills or leaks of petroleum products. The discussion
Examines the effects on odor detection and recognition of adding
includes potential risks of basic components and products of concern.
oxygenates such as methyl tertiary butyl ether (MTBE), ethyl tertiary butyl
Environmental factors that may affect exposure and a brief summary of other
ether (ETBE), and tertiary amyl methyl ether (TAME), to gasoline. Commercial
exposure considerations are also included. Pages: 51
grade MTBE is also evaluated for its taste threshold in water. The odor
detection threshold is the minimum concentration at which 50 % of a given
August 2001 | Product Number: I46890 | Price: $90.00
population can differentiate between a sample containing the odorant and a
sample of odor-free air. The recognition threshold is the minimum
Publ 4743
concentration at which 50 % of a given population can recognize the
Hazard Narrative for Tertiary-Butyl Alcohol (TBA),
odorant. The addition of 11 % to 15 % by volume MTBE or 15 % by volume
CAS Number 75-65-0
of TAME or ETBE reduce the odor detection and recognition thresholds of
gasoline. Pages: 76
The purpose of this investigation was to conduct a quantitative risk
January 1994 | Product Number: I45920 | Price: $86.00
assessment according to U.S. Environmental Protection Agency guidelines in
which data on the mode of action by which TBA induced renal tumors in rats
and thyroid tumors in mice was considered. When data from animal studies,
140
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such as the TBA bioassays, are extrapolated to humans to provide estimates
Publ 4594
of lifetime cancer risks, then potential differences in pharmacokinetics
A Critical Review of Toxicity Values and an Evaluation of the
(metabolism) and pharmacodynamics (sensitivity and mode of action)
Persistence of Petroleum Products for Use in Natural Resource
between the animal species and humans is considered in the estimation of
Damage Assessments
human equivalent doses and in extrapolation from high doses typically used
in the animal bioassays to low doses to which humans may be potentially
This document and accompanying 3.5-in. diskette provide a review of the
exposed. Pharmacokinetic, toxicity, and mode of action data for TBA were
literature (post-1970) on the toxicity of crudes and oil products in aquatic
reviewed and data selected for quantitative dose-response modeling.
environments. Some 748 toxicity values for fish, invertebrates, and algae are
Pages: 76
assembled into a database-OILTOX. LC50 values can be identified as well
November 2005 | Product Number: I47430 | Price: $161.00
as information on taxonomic groups and toxicity endpoints of interest. Key
methodological aspects of toxicity tests can be made as well as
determinations of which test procedures have a significant impact on results.
Publ 45592
Users need 640 KB RAM, DOS 2.0 or higher, and at least a 2 MB hard disk.
Results of Toxicological Studies Conducted for the American
Text may be downloaded onto a diskette and stored as a file or printed.
Petroleum Institute Health and Environmental Sciences Department
Pages: 196
Lists and provides the results through December 1994 of all toxicological
January 1995 | Product Number: I45940 | Price: $128.00
studies performed on petroleum-based materials, including gasoline and
gasoline streams, middle distillates, lubes, heavy fuels, solvents, shale oils,
Pollution Prevention
and miscellaneous products. It also provides details of the tests performed
and the species tested. A three-ring binder is provided to house this edition
Publ 300
and future updates. Pages: 190
The Generation and Management of Waste and Secondary
January 1995 | Product Number: I45592 | Price: $86.00
Materials in the Petroleum Refining Industry
In 1989, API initiated a census survey of domestic refineries to document
Natural Resource Damage Assessment
the management of waste and secondary materials in 1987 and 1988.
Outstanding responses by the refineries (115 out of the total U.S. population
Publ 304
of 176 refineries participated) aided in making confident estimates of the
Evaluation of Restoration Alternatives for Natural Resources Injured
amount of waste managed by the U.S. refining industry. Pages: 184
by Oil Spills
February 1991 | Product Number: J30000 | Price: $80.00
Builds upon previous work in the field of oil spill impact assessment and
habitat restoration to assess the technical feasibility and practicality of
Publ 302
proactive restoration following oil spills and presents an approach for
Waste Minimization in the Petroleum Industry: A Compendium of
evaluating tradeoffs between natural recovery and active restoration. The
Practices
scenarios developed to represent a broad spectrum of possible oil spills
In early 1988, API undertook a project to develop a compendium of the
were based on selected case studies. The report concludes that in general,
waste minimization practices for several different segments of the petroleum
available restoration techniques are not very effective for enhancing natural
industry. The compendium discusses a large variety of practices that can and
recovery and may, in certain cases, cause more severe impacts than the oil
are being utilized by the industry to reduce both the volume and toxicity of
spill alone. Pages: 171
wastes. From “good housekeeping practices” for marketing facilities to the
1st Edition | October 1991 | Product Number: J30400 | Price: $90.00
recycling of solvents, stormwater, and other traditional waste streams at
refineries, the compendium illustrates the various practices available to
Publ 316
minimize wastes in the industry. Pages: 152
Identifying and Measuring Nonuse Values for Natural and
November 1991 | Product Number: J30200 | Price: $98.00
Environmental Resources: A Critical Review
Publ 303
Takes an in-depth look at the theoretical arguments for using the contingent
Generation and Management of Wastes and Secondary Materials:
value method (CVM) as a scientifically valid and reliable tool for valuing
nonuse public goods, specifically, environmental resources. The theory of
1989 Petroleum Refining Performance
option value is used to frame the concept of nonuse; prominent studies that
This report is a follow-up to Publ 300 and documents the results of the
feature nonuse measurement are highlighted. The potential biases of the
1989 Refining Solid Waste Survey. The quantitative results of the generation
CVM method are mentioned with suggestions on improving values.
of the 28 waste and residual streams and their management according to
Pages: 134
the environmental management hierarchy (i.e. source reduction, recycling,
August 1995 | Product Number: J31600 | Price: $65.00
treatment, and disposal) is presented. In addition, the document contains a
discussion of the state of source reduction activities underway within the
DR 342
industry, including a quantitation of source reduction achievements on the
28 streams, and the methods used to calculate source reduction. Pages: 93
Toxicity Bioassays on Dispersed Oil in the North Sea: June 1996
June 1992 | Product Number: J30300 | Price: $98.00
Field Trials
The purpose of the study described in this report was to gain more
Publ 311
information on water column impacts by taking advantage of the ongoing
Environmental Design Considerations for Petroleum Refining
efficacy and monitoring studies done by the Norwegian Clean Seas
Processing Units
Association for Operating Companies (NOFO) in order to conduct field
toxicity tests.
Demonstrates the application of pollution prevention concepts in the design
The goal of this study was to obtain field effects data using shipboard, real-
of a refinery crude processing unit. Included are realistic waste and emission
time toxicity tests with field water. These data can then be used in the future
reduction changes that would be economically and technically attractive to
to link field effects to laboratory toxicity data. Pages: 108
refiners. The document is intended to serve as a reference for refinery
designers during the preliminary design phase of building a new crude unit
June 2002 | Product Number: I34200 | Price: $151.00
or revamping an existing crude unit. Pages: 214
February 1993 | Product Number: J31100| Price: $160.00
This publication is a new entry in this catalog.
This publication is related to an API licensing, certification, or accreditation program.
141
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Publ 31101
Publ 331
Executive Summary: Environmental Design Considerations for
Environmental Performance Indicators: Methods for Measuring
Petroleum Refining Crude Processing Units
Pollution Prevention
Executive summary to Publ 311. Pages: 13
Presents methods that can be used to measure progress toward pollution
February 1993 | Product Number: J31101 | Price: $63.00
prevention. It investigates a series of measurement parameters presented in
five categories: program-based, activity-based, mass-based, normalized
Publ 312
efficiency, and concentration-based. Within each category of measures, the
Responding to Environmental Challenge: The Petroleum Industry
benefits and limitations are discussed and illustrated with industry
examples. Pages: 30
and Pollution Prevention
September 1994 | Product Number: J33100 | Price: $69.00
Informal proceedings of a pollution prevention plenary session held at API’s
1990 Health and Environment Annual Meeting. Speakers representing
Publ 333
federal and state government, public interest groups, and various petroleum
industry segments presented their views on pollution prevention. This
Generation and Management of Residual Materials
document also describes API’s initiatives for pollution prevention research.
This report is the fifth in a series of reports detailing waste and residual
Pages: 16
and management practices in the refining sector. It presents the results
1990 | Product Number: J31200 | Price: Free*
of the 1992-1993 survey and includes information on how the industry
has achieved compliance with the land disposal restrictions on Resource
Publ 317
Conservation and Recovery Act (RCRA) listed hazardous K-wastes
(K0448-K052). It also documents the influence of the primary sludge
Industry Experience with Pollution Prevention Programs
rule and new toxicity characteristic under RCRA. Pages: 170
The API Pollution Prevention Task Force has been actively involved in
February 1995 | Product Number: J33300 | Price: $109.00
promoting pollution prevention within the industry since 1990. Members of
the Task Force have accumulated a comprehensive body of knowledge on
Publ 336
the subject of pollution prevention and have compiled a resource brochure
on the key elements that make pollution prevention programs successful.
Management of Residual Materials: 1994, Petroleum Refining
Pages: 4
Performance
June 1993 | Product Number: J31700 | Price: Free*
This report is the sixth in a series of reports presenting the results of the API
Annual Refining Residual Survey. It provides a detailed assessment of the
Publ 324
size of refinery throughput, the types of crude oil utilized, the regions in which
Generation and Management of Residual Materials: Petroleum
the refineries are located, the types of wastewater treatment processes used,
Refining Performance 1990 Survey
the amounts of different residual streams produced and how they are
managed, and the average cost of residual stream management. Pages: 98
This document is third in a series that presents the results of API’s annual
August 1996 | Product Number: J33600 | Price: $109.00
survey of the types and amounts of wastes and residuals generated and
managed by the petroleum refining industry. For 1990, source reduction
Publ 339
activities doubled over the previous year. The quantity of residuals generated
increased to 18.2 million wet tons as compared to 16.3 million wet tons in
Management of Residual Materials: 1995, Petroleum Refining
1989. Much of the increased quantity reflects generation peaks associated
Performance
with construction and remediation activities. Two long-term trends are worth
This report is the seventh in a series of reports presenting the results of the
noting: (1) the amount of total residuals being recycled continues to rise,
API Annual Refining Residual Survey. Included in the report are detailed
and (2) the amount of hazardous wastes going to land treatment and
assessments of generated quantities and management practices for 14
disposal continues to fall. Pages: 123
individual and 2 combined residual streams, trends in management
August 1993 | Product Number: J32400 | Price: $97.00
practices, average costs for selected residual stream management, types of
wastewater treatment systems employed at refineries, pollution prevention
Publ 329
activities, refinery capacities, and regions in which refineries are located. The
Generation and Management of Residual Materials: Petroleum
data in this report indicate a decrease of greater than 25 % in the quantity of
Refining Performance 1991 Survey
residuals generated by the refining industry from 1994 to 1995. Further, the
industry trend towards increased recycling of residuals has continued. In
This document is the fourth in a series that describes the 1991 data from
1995, over half of the refinery residuals generated were recycled rather than
API’s annual survey of the types and amounts of residual materials
being treated or disposed. Pages: 106
generated and managed by the refining industry. In 1991, the industry
July 1997 | Product Number: J33900 | Price: $109.00
generated 14.8 million wet tons of residual materials-the smallest quantity
generated since API began this collection effort in 1987. The industry also
reported that pollution prevention activities accounted for a reduction in
Publ 345
715,000 wet tons of materials. A trend analysis was performed on the last
Management of Residual Materials: 1996 Petroleum Refining
five years. Oil companies can use the data in this report to compare their
Performance
residual generation and management practices with the rest of the industry.
This report is the eighth in a series of reports presenting the results of the API
Pages: 172
Annual Refining Residual Survey. Included in the report are detailed
June 1994 | Product Number: J32900 | Price: $109.00
assessments of generated quantities and management practices for 14
residual streams representing approximately 80 % of all residuals managed
at U.S. refineries. Industry trend towards increased recycling of residuals has
continued. In 1996, well over half of the refinery residuals generated were
recycled rather than being treated or disposed. Pages: 106
June 1998 | Product Number: J34500 | Price: $109.00
142
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Bulletin No. 12
Soil and Groundwater Research
No-Purge Sampling: An Approach for Long-Term Monitoring
October 2000
Publ 4722
Groundwater Sensitivity Toolkit-Users Guide, Version 1.0
Bulletin No. 13
Dissolution of MTBE from a Residually Trapped Gasoline Source
API and the California MTBE Research Partnership have produced a new
software utility to help site managers, water purveyors, and regulators
September 2001
evaluate the sensitivity of a groundwater resource to a potential release of
compounds of concern [e.g. a methyl tertiary-butyl ether (MTBE)-oxygenated
Bulletin No. 14
fuel]. The toolkit examines three aspects of sensitivity: resource value,
Predicting the Effect of Hydrocarbon and Hydrocarbon-Impacted Soil
receptor vulnerability, and natural sensitivity. The user supplies site-specific
on Groundwater
information, and the toolkit returns a “scorecard” addressing the three
aspects of sensitivity. Although this utility was designed with petroleum
September 2001
hydrocarbon releases in mind, it can be used when dissolved chlorinated
and inorganic compounds are the chemicals of concern. The toolkit runs on
Bulletin No. 15
Microsoft Excel® and comes with a user’s guide. Pages: 51
Vadose Zone Natural Attenuation of Hydrocarbon Vapors: An
August 2002 | Product Number: I47220 | Price: $65.00
Emperical Assessment of Soil Gas Vertical Profile Data
December 2001
API Soil and Groundwater Research Bulletins
API Soil and Groundwater Research bulletins summarize research results
Bulletin No. 16
from project overseen by API’s Soil and Groundwater Technical Task Force.
Migration of Soil Gas Vapors to Indoor Air: Determining Vapor
The Task Force disseminates information and research results through
Attenuation Factors Using a Screening-Level Model and Field Data
publications, presentations, and interaction with industry clients and
from the CDOT-MTL
regulatory agencies.
April 2002
The bulletins listed below can be downloaded at https://www.api.org/
oil-and-natural-gas/environment/clean-water/ground-water/bulletins
Bulletin No. 17
Identification of Critical Parameters for the Johnson and Ettinger
Bulletin No. 1
(1991) Vapor Intrusion Model
Summary of Processes, Human Exposures and Remediation
May 2002
Technologies Applicable to Low Permeability Soils
September 1996
Bulletin No. 18
Answers to Frequently Asked Questions About Managing Risk at
Bulletin No. 3
LNAPL Sites
Ten Frequently Asked Questions About MTBE in Water
June 2018
March 1998
Bulletin No. 19
Bulletin No. 5
Evaluation of Small-Volume Releases of Ethanol-Blended Gasoline
Evaluation of Sampling and Analytical Methods for Measuring
at UST Sites
Indicators of Intrinsic Bioremediation
October 2003
March 1998
Bulletin No. 20
Bulletin No. 8
Answers to Frequently Asked Questions About Ethanol Impacts to
Characteristics of Dissolved Petroleum Hydrocarbon Plumes: Results
Groundwater
from Four Studies
December 2003
December 1998
Bulletin No. 21
Bulletin No. 9
Evaluation of Potential Vapor Transport to Indoor Air Associated with
Non-Aqueous Phase Liquid (NAPL) Mobility Limits in Soil
Small-Volume Releases of Oxygenated Gasoline in the Vadose Zone
June 2000
January 2005
Bulletin No. 10
Bulletin No. 22
Simulation of Transport of Methyl Tert-Butyl Ether (MTBE) to
Maximum Potential Impacts of Tertiary Butyl Alcohol (TBA) on
Ground-Water from Small-Volume Releases of Gasoline in the
Groundwater from Small-Volume Releases of Ethanol-Blended
Valdose Zone
Gasoline in the Vadose Zone
June 2000
January 2005
Bulletin No. 11
Bulletin No. 23
Strategies for Characterizing Subsurface Releases of Gasoline
The Impact of Gasohol and Fuel-Grade Ethanol on BTX and Other
Containing MTBE
Hydrocarbons in Ground Water: Effect on Concentrations Near a
August 2000
Source
December 2005
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This publication is related to an API licensing, certification, or accreditation program.
143
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Bulletin No. 24
Publ 4627
Downward Solute Plume Migration: Assessment Significance and
In-Situ and On-Site Biodegradation of Refined and Fuel Oils: A
Implications for Characterization and Monitoring of “Diving Plumes”
Review of Technical Literature 1988-1991
April 2006
Reviews more than 200 technical articles published between 1988 and
1991 in the area of on-site and in-situ bioremediation of petroleum
Bulletin No. 25
hydrocarbons. It focuses specifically on current field and laboratory research
Remediation Progress at California LUFT Sites: Insights from the
related to petroleum hydrocarbon biodegradation including biodegradation of
GeoTracker Database
crude oil and solvents. Recent work in fate and transport modeling that can
be applied to petroleum hydrocarbon contamination in groundwater is also
February 2012
covered. The review is designed to complement an earlier (pre-1988) review
published by the U.S. Navy. Pages: 146
Bulletin No. 26
June 1995 | Product Number: I46270 | Price: $67.00
Tertiary Butyl Alcohol (TBA) Biodegradation: Some Frequently Asked
Questions
Publ 4633
March 2012
Barium in Produced Water: Fate and Effects in the Marine
Environment
CONTAMINANT FATE AND TRANSPORT
Provides a summary of what is currently known about the physical and
Publ 4531
chemical behavior of barium in produced water and in the ocean. It
discusses the factors that influence the rate of precipitation of barium as
Chemical Fate and Impact of Oxygenates in Groundwater: Solubility
barite. The toxicity of barium to marine and freshwater organisms and
of BTEX from Gasoline-Oxygenate Mixtures
humans is discussed in relation to the concentrations and forms in which it
Oxygenated hydrocarbon compounds may be added to gasoline mixtures to
occurs in aquatic environments. Pages: 68
improve emission quality and octane ratings or to conserve petroleum
September 1995 | Product Number: I46330 | Price: $65.00
resources, which may alter the behavior of dissolved organic compounds in
groundwater following a fuel spill. This study evaluates the effects of
Publ 4643
oxygenate additives such as methanol or methyl tertiary-butyl ether on the
aqueous solubility of dissolved aromatic hydrocarbons (benzene, toluene,
Estimation of Infiltration and Recharge for Environmental Site
ethylbenzene, and the isomers of xylene, collectively referred to as BTEX)
Assessment
from gasoline. It also explores the nature of the dissolved contaminant
A risk-based corrective action analysis of a site suspected of chemical
plumes that could develop from a spill of gasoline containing methanol.
contamination requires site-specific knowledge of the rate water infiltrates
Pages: 110
through the soil to the water table. A comprehensive discussion of the current
August 1991 | Product Number: I45310 | Price: $67.00
physical/chemical methods and mathematical models available to quantify
those rates along with suggestions for selecting an appropriate technique,
Publ 4593
depending on site conditions, are provided in this report. Pages: 204
Transport and Fate of Non-BTEX Petroleum Chemicals in Soils and
July 1996 | Product Number: I46430 | Price: $105.00
Groundwater
This literature survey documents available information on the chemical
Publ 4654
composition of petroleum products and the subsurface fate and transport of
Field Studies of BTEX and MTBE Intrinsic Bioremediation
selected non-BTEX (benzene, toluene, ethylbenzene, and xylenes)
A gasoline release field site in the Coastal Plain of North Carolina was
constituents of these products. The evaluation focuses on a representative
monitored for more than three years to allow calculation of in-situ
group of 12 hydrocarbons and hetero-organic compounds based on their
biodegradation rates. Laboratory microcosm experiments were performed to
abundance in petroleum products and anticipated future interest from
further characterize the biodegradation of benzene, toluene, ethylbenzene,
regulatory agencies. Pages: 200
and xylenes (BTEX) and methyl tertiary-butyl ether (MTBE) under ambient, in-
September 1994 | Product Number: I45930 | Price: $71.00
situ conditions. Finally, groundwater modeling studies were conducted to
facilitate the interpretation of field data and to evaluate various approaches
Publ 4601
for predicting the fate and effects of these gasoline constituents in the
Transport and Fate of Dissolved Methanol, MTBE and Monoaromatic
subsurface. Pages: 244
Hydrocarbons in a Shallow Sand Aquifer
October 1997 | Product Number: I46540 | Price: $82.00
Describes a field investigation into the effect of oxygenates methanol and
methyl tertiary-butyl ether (MTBE) on the fate and transport of benzene,
Publ 4674
toluene, ethylbenzene, and xylenes (BTEX) in groundwater. Natural gradient
Assessing the Significance of Subsurface Contaminant Vapor
tracer experiments were conducted to simulate the transport of dissolved
Migration to Enclosed Spaces-Site-Specific Alternative to Generic
plumes resulting from subsurface releases of oxygenated fuels. In these
Estimates
experiments, methanol, MTBE, and BTEX concentrations were monitored by
sampling from a dense network of multilevel piezometers, and plume
Vapors in enclosed spaces pose two levels of concern. First, enclosed-space
contours were mapped through application of moment analysis. A laboratory
vapors may be found at concentrations near those that pose immediate
study on the effects of methanol and MTBE on the biodegradation of BTEX in
flammability and/or health risks. These sites warrant immediate attention
groundwater was also conducted. The relative mobility and persistence of
and response as required by most state and federal regulatory guidance. In
BTEX and the oxygenates were characterized based on field and laboratory
the second class of sites, concentrations are lower and the concern is for
study data. Pages: 338
longer term health risks. This report focuses exclusively on this second class
of sites, where advection and diffusion occur through a soil layer and into an
April 1994 | Product Number: I46010 | Price: $134.00
enclosed space, and time is available to adequately address the problem on
a site-specific basis. The options considered in this document include the
following:
direct measurement through sampling of enclosed-space vapors,
use of near-foundation or near-surface soil gas sampling results,
144
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use of site-specific homogeneous and layered soil diffusion coefficients in
REMEDIAL TECHNOLOGIES
generic algorithms, and
assessment of bioattenuation potential. Pages: 56
DR 225
December 1998 | Product Number: I46740 | Price: $86.00
Remediation of a Fractured Clay Till Using Air Flushing: Field
Experiments at Sarnia, Ontario
Publ 4734
This study was conducted over a three-year period at a well-characterized
Modeling Study of Produced Water Release Scenarios
test site located in Canada near Sarnia, Ontario. A synthetic gasoline blend
Provides a scientific basis for operators, regulators, and landowners to
of known mass, volume, and composition was released into a test cell.
determine if assessment or remediation of produced water releases will
Samples were collected and analyzed for gasoline range organics to
provide a meaningful environmental benefit.
establish the three-dimensional distribution of the release. Conventional air
flushing technologies, soil vapor extraction and in-situ air sparging, were able
The two principal research objectives of this study are (1) the identification of
to remove ~40 % of the spilled mass during the initial two months of
produced water release scenarios that have a potential to cause groundwater
operation. Following active remediation, primarily low-volatility compounds
quality impairment in homogeneous subsurface geologic profiles and (2) the
remained in the soil and almost no benzene or toluene remained. Based on
prediction of chloride movement through the vadose zone for different release
mass balance data, a significant portion of the benzene, toluene,
scenarios. Secondary objectives of the study included evaluation of the effect
ethylbenzene, and xylene compounds was biodegraded. Pages: 220
of heterogeneity on the migration of chloride through the vadose zone, the
impact of repeat releases, and the effect on groundwater quality of surface
October 1998 | Product Number: I00225 | Price: $105.00
soil restoration by revegetation and soil leaching.
The sensitivity analysis performed in this study provides an overview of the
Publ 4525
likelihood of groundwater impairment for large release volumes (100 bbls and
A Compilation of Field-Collected Cost and Treatment Effectiveness
10,000 bbls). Assuming homogeneous unsaturated zone soil profiles, the
Data for the Removal of Dissolved Gasoline Components from
results of over 1000 modeled release scenarios reveal that 49 % of single-
Groundwater
event releases do not cause impairment of groundwater above drinking water
standards for chloride (250 mg/L) in a monitoring well that is adjacent to the
Documents, summarizes, and evaluates cost and treatment effectiveness
edge of the release. In 70 % of these scenarios, chloride concentrations in
data for air stripping and carbon adsorption systems designed to remove
groundwater do not exceed 1000 mg/L. Although these numbers give no
dissolved petroleum hydrocarbons from groundwater. The compounds of
information about the fate of chloride from a specific produced water release,
primary interest were benzene, toluene, ethylbenzene, and xylene isomers
they do indicate that a release does not necessarily cause groundwater
(BTEX) as well as the oxygenates methyl tertiary-butyl ether and isopropyl
impairment. Pages: 124
ether. Operating data were gathered from 57 field sites throughout the
United States, and treatment system profiles were generated for each site.
January 2005 | Product Number: I47340 | Price: $134.00
The data will be used to assist companies in planning pump-and-treat
remediation systems for removal of BTEX and oxygenates from groundwater.
Publ 4758
Pages: 240
Strategies for Addressing Salt Impacts of Produced Water Releases
November 1990 | Product Number: I45250 | Price: $86.00
to Plants, Soil, and Groundwater
The exploration and production industry uses great care during the handling
Publ 4609
and disposal of the produced water that is generated as part of oil and gas
In-Situ Air Sparging: Evaluation of Petroleum Industry Sites and
production. However, unintentional releases can occur. Depending on the
Considerations for Applicability, Design and Operation
chemical composition of the produced water and the nature of the local
environment, salts associated with such releases can impair soils, vegetation,
Describes the important literature findings as well as the hands-on
and water resources.
experiences of the petroleum industry at 59 air sparging sites. Design and
operational data are analyzed for relationships that can be used to optimize
Provides a collection of simple rules of thumb, decision charts, models, and
the technology or provide a better understanding of its fundamental
summary information from more detailed guidance manuals to help you
address the following assessment and response issues:
processes. Topics covered include: site characterization; pilot testing; system
design and installation; and system operation, monitoring, and performance.
Will a produced water release cause an unacceptable impact on soils,
Pages: 132
plants, and/or groundwater?
In the event of such an impact, what response actions are appropriate
May 1995 | Product Number: I46090 | Price: $105.00
and effective? Pages: 29
1st Edition | September 2006 | Product Number: I47580 | Price: $76.00
Publ 4631
Petroleum Contaminated Low Permeability Soil: Hydrocarbon
Publ 4784
Distribution Processes, Exposure Pathways and In-Situ Remediation
Quantification of Vapor Phase-Related Natural Source Zone
Technologies
Depletion Processes
Presents a set of 10 papers on light nonaqueous phase liquids (LNAPLs)
in low permeability soils. Collectively, the papers address four key areas:
Natural source zone depletion (NSZD) has emerged as an important concept
(1) processes affecting the migration and removal of LNAPLs; (2) exposure
within the realm of environmental remediation. NSZD is a term used to
potential posed by clay soil and hydrocarbons via soil, groundwater, and
describe the collective, naturally occurring processes of dissolution,
air pathways; (3) models for predicting LNAPL removal; and (4) techniques
volatilization, and biodegradation that results in mass losses of light non-
of remediation. Pages: 298
aqueous phase liquid (LNAPL) petroleum hydrocarbon constituents from the
subsurface.
September 1995 | Product Number: I46310 | Price: $95.00
This document provides practical guidance on NSZD theory, application,
Publ 4655
measurement methods, and data interpretation. It is intended to be used by
practitioners to help plan, design, and implement NSZD monitoring
Field Evaluation of Biological and Non-Biological Treatment
programs in support of petroleum hydrocarbon site remediation. Pages: 124
Technologies to Remove MTBE/Oxygenates from Petroleum Product
1st Edition | May 2017 | Product Number: I47840 | Price: $131.00
Terminal Wastewaters
A pilot/demonstration study was conducted on three treatment
technologies-the fluidized bed biological reactor process, the activated
sludge process incorporated with iron flocculation, and the ultraviolet light/
This publication is a new entry in this catalog.
This publication is related to an API licensing, certification, or accreditation program.
145
Health and Environmental Issues
To purchase individual API standards, visit apiwebstore.org
hydrogen peroxide process-to evaluate their effectiveness in the treatment
software. Four example problem applications are presented which highlight
of petroleum marketing terminal wastewater contaminated with methyl tert-
model use, parameter estimation using the API LNAPL Parameters Database,
butyl ether (MTBE). Contaminated groundwater was the primary constituent
and limitations of scenario-based models.
of the wastewater, which also contained benzene, toluene, ethylbenzene,
January 2007 | Software and documentation can be downloaded at
and xylenes (BTEX). All three technologies were able to remove at least 95 %
of the MTBE and BTEX in the feed waters. Pages: 194
ground-water/lnapl/ldrm
August 1997 | Product Number: I46550 | Price: $134.00
Publ 4762
Publ 4671
API LNAPL Transmissivity Workbook: A Tool for Baildown Test
Technical Bulletin on Oxygen Releasing Materials for In-Situ
Analysis-User Guide
Groundwater Remediation
Oxygen releasing materials (ORMs) are commercially available materials that
LNAPL transmissivity is a measure of lateral mobility of free-product
are being used to enhance bioremediation treatment of petroleum
hydrocarbon liquid within the groundwater environment. The magnitude of
hydrocarbon contaminated groundwater aquifers. This technical bulletin
LNAPL transmissivity has been suggested as a possible endpoint criterion for
provides a systematic approach for evaluating the utility of ORM treatment
LNAPL mass removal using LNAPL hydraulic recovery systems. Such
and for designing ORM installations. It summarizes the current state of
hydraulic recovery systems include skimmer wells, single-pump wells, dual-
understanding of this technology to provide guidance for site managers
pump wells, and trenches. Coupled with the LNAPL CSM, the magnitude of
evaluating options for enhanced groundwater remediation. Pages: 52
LNAPL transmissivity will assist in the selection of recovery system. As such,
methods and their consistent application for estimating LNAPL transmissivity
July 1998 | Product Number: I46710 | Price: $76.00
are significant. Perhaps the simplest methods for estimating LNAPL
transmissivity are borehole slug test methods, or baildown tests, in which a
Publ 4715
volume of LNAPL is rapidly removed from a well and the rate of fluid-level
Evaluating Hydrocarbon Removal from Source Zones and its Effect
recovery (water and LNAPL) is measured and analyzed. Several analytical
on Dissolved Plume Longevity and Concentration
methods are available to analyze the data from baildown tests to estimate
LNAPL transmissivity and described herein. Following a brief description of
Provides valuable information and utilities for regulators and practitioners
suggested well configuration, pre-test and test measurements and methods,
interested in understanding the possible benefits of free-product removal. This
application of the spreadsheet tool is discussed. Subsequent sections
report provides theory and concepts needed to evaluate light nonaqueous
provide a more detailed discussion of significant parameters and basis for
phase liquid (LNAPL) source distribution, chemistry, dissolution, and the
the various analysis procedures. A number of example applications are
effects various remediation strategies may have on risk reduction for the
presented. Further details on the different methods are provided in the
groundwater and vapor exposure pathways. The companion software, API-
appendices. Pages: 40
LNAST, links the multiphase and chemical processes controlling in-situ LNAPL
April 2016 | Product Number: I47620 | For a free copy of this document,
distribution, mobility, and cleanup to quantify estimates of the time-dependent
concentrations within the LNAPL source and the down gradient dissolved
please visit https://www.api.org/~/media/
plume. API-LNAST users can screen whether incremental LNAPL removal
4762%20LNAPL%20Tn%20wkbk%20Baildown%20userguide%20Apr20
provides any risk-reduction benefit over a time frame of interest, e.g. 30 years.
16%20(2).pdf
September 2002 | Software and documentation can be downloaded at
SITE CHARACTERIZATION
ground-water/lnapl/evaluating-hydrocarbon-removal
Publ 4599
Publ 4730
Interlaboratory Study of Three Methods for Analyzing Petroleum
Groundwater Remediation Strategies Tool
Hydrocarbons in Soils
Provides strategies for focusing remediation efforts on (1) the change in
Presents the results of an interlaboratory study of three methods-diesel-
contaminant mass flux in different subsurface transport compartments (e.g.
range organics, gasoline-range organics, and petroleum hydrocarbons-used
the vadose zone, smear zone, or a zone within an aquifer of interest) and
to analyze hydrocarbons in soils. Each method is validated, its performance
(2) the change in remediation timeframe.
judged from measurements of accuracy and precision, and practical
In this approach, groundwater flow and contaminant concentration data are
qualification levels are estimated for each method. The full text of each
combined to estimate the rate of contaminant mass transfer past user-
method is included in the report. Pages: 166
selected transects across a contaminant plume. The method provides the
July 1994 | Product Number: I47990 | Price: $105.00
user with a means to estimate the baseline mass flux and remediation
timeframe for various transport compartments and then evaluate how
Publ 4635
different remedies reduce the mass flux and the remediation timeframe in
Compilation of Field Analytical Methods for Assessing Petroleum
each transport compartment. Pages: 71
Product Releases
December 2003 | Product Number: I473000 | Price: $138.00
Presents a compilation of the most widely used field analytical methods
Publ 4760
available to perform on-site analyses of organic compounds in soil and
groundwater. These methods include total organic vapor analyzers, field gas
LNAPL Distribution and Recovery Model (LDRM)
chromatography, immunoassay, infrared analyzers, and dissolved oxygen/
Simulates the performance of proven hydraulic technologies for recovering free-
oxidation-reduction potential electrodes. Practical applications and
product petroleum liquid releases to groundwater. The LDRM provides
limitations of each method are discussed and an objective-oriented data
information about light nonaqueous phase liquid (LNAPL) distribution in
quality classification scheme is presented to assist in selecting an
porous media and allows the user to estimate LNAPL recovery rates, volumes,
appropriate method. Information is also presented on emerging
and times. Documentation for the LDRM is provided in two volumes.
technologies. Pages: 100
Volume 1-Distribution and Recovery of Petroleum Hydrocarbon Liquids in
December 1996 | Product Number: I46350 | Price: $95.00
Porous Media-documents the LDRM and provides background information
necessary to characterize the behavior of LNAPL in porous media with regard to
performance of LNAPL liquid recovery technologies. Volume 2-User and
Parameter Selection Guide-provides step-by-step instructions for the LDRM
146
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This publication is related to an API licensing, certification, or accreditation program.
Health and Environmental Issues
To purchase individual API standards, visit apiwebstore.org
Publ 4657
site assessment to site closure. The decision-tree charts are supported by
Effects of Sampling and Analytical Procedures on the Measurement
quality control packages to increase the credibility of the data by
documenting method performance. The publication also provides training
of Geochemical Indicators of Intrinsic Bioremediation: Laboratory
suggestions for personnel who will perform the testing. Easy to use checklists
and Field Studies
for field quality control and formal documentation are included. Pages: 88
Evaluates the effects of various sampling and analytical methods of collecting
August 1998 | Product Number: I46700 | Price: $95.00
groundwater geochemical data for intrinsic bioremediation studies. Sampling
and analytical methods were tested in the laboratory and in the field. Several
Publ 4699
groundwater sampling and analytical methods may be appropriate for
Strategies for Characterizing Subsurface Releases of Gasoline
measuring geochemical indicators of intrinsic bioremediation. The methods
vary in accuracy, level of effort, and cost. Pages: 86
Containing MTBE
November 1997 | Product Number: I46570 | Price: $67.00
Applies the principles of risk-informed decision making to the evaluation of
methyl tertiary-butyl ether (MTBE)-affected sites by adding exposure and risk
Publ 4658
considerations to the traditional components of the corrective action
Methods for Measuring Indicators of Intrinsic Bioremediation:
process. The risk factors at a given site are evaluated through a “conceptual
site model,” which is an inventory of all known or potential oxygenate
Guidance Manual
sources, pathways, and receptors. Based on these risk factors, three levels of
Intended to be a resource for practitioners of intrinsic bioremediation in
assessment are defined: standard, limited, and detailed. The appropriate
allowing selection of sampling and analytical methods that meet project-
level of assessment is initially determined based on receptor data, which can
specific and site-specific needs in scoping field investigations, providing
typically be obtained from a survey of nearby wells and land uses. A
procedures that will improve the representative quality of the collected data,
subsurface investigation may then be conducted to obtain information on
and considering potential biases introduced into data through the sampling
sources and pathways. The level of assessment can be “upgraded” or
and analytical techniques employed in the site investigation. Pages: 96
“downgraded” as warranted by the resulting source and pathway
information. Includes a review of the chemical properties and subsurface
November 1997 | Product Number: I46580 | Price: $76.00
behavior of MTBE and other oxygenated fuel additives. It also provides an
overview of characterization monitoring issues at oxygenate release sites, as
Publ 4659
well as a detailed review of the tools and techniques used for subsurface
Graphical Approach for Determining Site-Specific Dilution-
assessment. The expedited site assessment process and the use of modern
Attenuation Factors (DAFs): Technical Background Document and
direct-push tools are particularly emphasized, since these approaches are
User’s Guide
especially well suited for use at MTBE-affected sites. Pages: 120
February 2000 | https://www.api.org/oil-and-natural-gas/environ-
The DAF plays a key role in assessing potential impact from the soil-to-
ment/clean-water/ground-water/oxygenates/site-characterization
groundwater pathway at sites where groundwater quality is, or may be,
affected by a leak, spill, or other accidental release of hydrocarbons or other
chemicals of concern. A simplistic, graphically-based approach for
Publ 4709
determining generic and site-specific DAFs was developed, allowing for
Risk-Based Methodologies for Evaluating Petroleum Hydrocarbon
varying levels of site specificity. Currently, to develop a DAF, one must make
Impacts at Oil and Natural Gas E&P Sites
complicated calculations by hand or use computer-based modeling
software. This publication consists of two documents. The first document
The process of calculating human health risk-based screening levels for total
describes the technical basis for the graphical approach for determining site-
petroleum hydrocarbons (TPH) is described in an easy-to-understand
specific dilution attenuation factors. The second document, the user’s guide,
question and answer format. [Risk-based screening levels (RBSLs) are
provides a concise set of instructions for use of the graphical approach.
chemical-specific concentrations in environmental media that are
Pages: 233
considered protective of human health.] Risk assessment concepts
developed by the U.S. Environmental Protection Agency and research groups
February 1998 | Product Number: I46590 | Price: $128.00
such as the Petroleum Environmental Research Forum and the Total
Petroleum Hydrocarbon Criteria Working Group are used to calculate RBSLs
Publ 4668
for TPH in crude oil and condensates obtained from around the world. These
Delineation and Characterization of the Borden MTBE Plume: An
methodologies were also applied to polyaromatic hydrocarbons, metals, and
Evaluation of Eight Years of Natural Attenuation Processes
benzene in TPH. Additional resources contained in this manual include a
description of the physical and chemical characteristics of crude oil,
In 1988, a natural gradient tracer test was performed in the shallow sand
condensate, and exploration and production (E&P) wastes (contrasted with
aquifer at Canada Forces Base Borden to investigate the fate of a methyl
refined products), a summary of the federal regulatory status of E&P wastes,
tertiary-butyl-ether (MTBE) plume introduced into the aquifer. Solutions of
and a listing of key equations used for calculating RBSLs. Pages: 100
groundwater mixed with oxygenated gasoline were injected below the water
table along with chloride (Cl-), a conservative tracer. The migration of benzene,
February 2001 | Product Number: I47090 | Price: $90.00
toluene, ethylbenzene, and xylenes (BTEX); MTBE; and Cl- was monitored in
detail for about 16 months. The mass of BTEX in the plume diminished
Publ 4711
significantly with time due to intrinsic biodegradation. MTBE, however, was not
Methods for Determining Inputs to Environmental Petroleum
measurably attenuated. In 1995-1996, a comprehensive groundwater
Hydrocarbon Mobility and Recovery Models
sampling program was undertaken to define the mass of MTBE still present in
the aquifer. Only about 3 % of the initial MTBE mass was found, and it is
This publication is an invaluable reference for operators, consultants and
hypothesized that biodegradation played an important role in its attenuation.
regulators responsible for cleanup of subsurface petroleum releases. Important
Additional evidence is necessary to confirm this possibility. Pages: 88
fluid and soil property parameters are explained. Methods to measure each
June 1998 | Product Number: I46680 | Price: $67.00
parameter are presented in order of relevance for use in environmental free-
product mobility/recovery assessments. Fluid property parameters covered
Publ 4670
include density, viscosity, surface tension, and interfacial tension. Laboratory-
Selecting Field Analytical Methods-A Decision-Tree Approach
scale soil property parameters include: capillary pressure vs. saturation,
relative permeability vs. saturation, water and nonaqueous phase liquid
Presents a decision-tree approach for selecting and using field analytical
saturation, and Brooks-Corey and van Genuchten model parameters. Field-
methods for on-site analyses of organic compounds in soil, groundwater,
and soil gas samples at petroleum release sites. This approach will assist
project or site managers with guidance for on-site investigations from initial
This publication is a new entry in this catalog.
This publication is related to an API licensing, certification, or accreditation program.
147
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